Home
Class 11
CHEMISTRY
It requires 40.0mL of 0.50M Ce^(4+) to t...

It requires `40.0mL` of `0.50M Ce^(4+)` to titrate `10.0 mL` of `1.0MSn^(2+) "to" Sn^(4+)`. What is the oxidation state of cerium in the reduced product?

Text Solution

Verified by Experts

`Sn^(2+)rarrSn^(4+)+2e`
`"ne"+Ce^(4-)rarrCe^((4-n)+)`
`Meq .of Ce^(4+)=Meq. Of Sn^(2+)`
` 40xx0.5xxn=1xx2xx10.0 rArr n=1`
`:. Ce^(4+)+erarrCe^(3+)`
thus oxidation state of `Ce` in reduced state is `+3`.
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS

    P BAHADUR|Exercise Exercise(2) previous year numerical problems|30 Videos
  • REDOX REACTIONS

    P BAHADUR|Exercise Exercise 3(A) Objective problems|81 Videos
  • RADIO ACTIVITY

    P BAHADUR|Exercise Exercies 9|99 Videos
  • THERMOCHEMISTRY

    P BAHADUR|Exercise Exercise 9 Advance numerical problems|31 Videos

Similar Questions

Explore conceptually related problems

It requires 40mL of 1 M Ce^(4+) to titrate 20mL of 1 M Sn^(2+) " to "Sn^(4+) . What is the oxidation state of the cerium in the product?

A volume of 12.5 mL of 0.05 M SeO_(2) reacts with 25 mL of 0.1 M CrSO_(4) which is oxidised to Cr^(3+) . To what oxidation state was the selenium converted by the reaction ?

60ml of 0.1M HCl is mixed with 40ml of 0.05M H_(2)SO_(4) .The "pH" value of the resulting solution is

P BAHADUR-REDOX REACTIONS-Exercise(8) Statement:Explanation type problems
  1. It requires 40.0mL of 0.50M Ce^(4+) to titrate 10.0 mL of 1.0MSn^(2+) ...

    Text Solution

    |

  2. Statement Oxidation number of Cu in CuH is -1 Explanation Cu is plac...

    Text Solution

    |

  3. Statement Oxidation state of H is +1 in CuH(2) and -1 in CaH(2) Expl...

    Text Solution

    |

  4. Statement Oxygen atom in both O(2) and O(3) has oxidation number zero....

    Text Solution

    |

  5. Statement N atom has two different oxidation states in NH(4)NO(2). E...

    Text Solution

    |

  6. Statement 2H(2)O(2)rarr2H(2)O+O(2) is autoredox change. Explanation ...

    Text Solution

    |

  7. Statement Oxidation number of metals in metal carbonyls is zero. Exp...

    Text Solution

    |

  8. Statement SO(2) can be used as reductant as well as oxidant. Explanat...

    Text Solution

    |

  9. Statement KMnO(4) is strong oxidant whereas Mn^(2+) is weaker reductan...

    Text Solution

    |

  10. Statement VO(2)^(+) and VO^(2+) both are called vanadyl ions. Explana...

    Text Solution

    |

  11. Statement In the reactions , 3As(2)S(3)rarr28HNO(3)+4H(2)Orarr6H(3)AsO...

    Text Solution

    |

  12. Statement In acidic medium equivalent weight of K(2)Cr(2)O(7) is 49. ...

    Text Solution

    |

  13. Statement Iodimetric titrations are redox titrations. Explanation The...

    Text Solution

    |

  14. Statement The redox titarations in which liberated I(2) is used as oxi...

    Text Solution

    |

  15. Statement KMnO(4) acts as oxidant as well as self indicator in its tit...

    Text Solution

    |

  16. Statement The equivalence point refers the condition where equivalents...

    Text Solution

    |

  17. Statement The equivalence weight of KMnO(4) when it is converted to K(...

    Text Solution

    |

  18. Statement The number of equivalent per mole of H(2)S used in its oxida...

    Text Solution

    |

  19. Statement Starch is generally used as absorption indicator in iodimetr...

    Text Solution

    |

  20. Statement The oxidation number of an element in its free or uncombined...

    Text Solution

    |