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Amount of oxalic acid present in a solut...

Amount of oxalic acid present in a solution can be determined by its titration with `KMnO_(4)` solution in the presence of `H_(2)SO_(4)`. The titration gives unsatisfactory result when carried out in the presence of `HCl`, because `HCl`:

A

gets oxidised by oxalic acid to chlorine

B

furnishes `H^(+)` ions in addition to those from oxalic acid

C

reduces permangante to `Mn^(2+)`

D

oxidises oxalic acid to carbon dioxide and water

Text Solution

Verified by Experts

The correct Answer is:
C

`HCl` being stronger reducing agent it reduces `MnO_(4)^(-)` to `Mn^(2+)` and result of titration become unsatisfactory.
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