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Consider the reactions : C((s))+2H(2(g...

Consider the reactions `:`
`C_((s))+2H_(2(g)) rarr CH_(4(g)), DeltaH=-X kcal`
`C_((g))+4H_((g)) rarr CH_(4(g)),DeltaH-X_(1)kcal`
`CH_(4(g))rarr CH_(3(g))+H_((g)), DeltaH=+Ykcal`
The average bond energy of `C-H` bond is `:`

A

`(X)/(4) kcal mol^(-1)`

B

`Y kcal mol^(-1)`

C

`(X_(1))/(4)kcal mol^(-1)`

D

`X_(1)kcal mol^(-1)`

Text Solution

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The correct Answer is:
To find the average bond energy of the C-H bond in methane (CH₄), we can analyze the given reactions and their enthalpy changes (ΔH). ### Step-by-Step Solution: 1. **Understanding the Reactions**: - The first reaction is: \[ C_{(s)} + 2H_{2(g)} \rightarrow CH_{4(g)}, \Delta H = -X \text{ kcal} \] - The second reaction is: \[ C_{(g)} + 4H_{(g)} \rightarrow CH_{4(g)}, \Delta H = -X_1 \text{ kcal} \] - The third reaction is: \[ CH_{4(g)} \rightarrow CH_{3(g)} + H_{(g)}, \Delta H = +Y \text{ kcal} \] 2. **Identifying the Bond Dissociation**: - In the third reaction, methane (CH₄) is dissociating into CH₃ and a hydrogen atom (H). The ΔH for this reaction is +Y kcal, indicating that energy is absorbed to break the C-H bond. 3. **Relating the Reactions**: - The enthalpy change for the dissociation of CH₄ into its constituent atoms can be related to the bond energies. When CH₄ dissociates, it breaks 4 C-H bonds: \[ CH_{4(g)} \rightarrow C_{(g)} + 4H_{(g)} \quad \text{(reverse of the second reaction)} \] - The enthalpy change for this reverse reaction will be +X₁ kcal. 4. **Setting Up the Equation**: - The total energy required to break all 4 C-H bonds in CH₄ can be expressed as: \[ 4 \times \text{(average bond energy of C-H)} = Y + X_1 \] - Here, Y is the energy required to break one C-H bond, and X₁ is the energy required to form CH₄ from C and 4H. 5. **Calculating Average Bond Energy**: - To find the average bond energy of one C-H bond, we rearrange the equation: \[ \text{Average bond energy of C-H} = \frac{Y + X_1}{4} \] ### Final Answer: The average bond energy of the C-H bond is: \[ \text{Average bond energy of C-H} = \frac{Y + X_1}{4} \text{ kcal} \]

To find the average bond energy of the C-H bond in methane (CH₄), we can analyze the given reactions and their enthalpy changes (ΔH). ### Step-by-Step Solution: 1. **Understanding the Reactions**: - The first reaction is: \[ C_{(s)} + 2H_{2(g)} \rightarrow CH_{4(g)}, \Delta H = -X \text{ kcal} ...
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