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The data given below are for vapour phas...

The data given below are for vapour phase reactions at constant pressure.
`C_(2)H_(6)rarroverset(*)(C_(2))overset(*)(H_(5))+overset(*)(H), DeltaH=-4200kJmol^(-1)`
`overset(*)(C_(2))H_(6) rarr C_(2)H_(4)+overset(*)(H), DeltaH=168kJ mol^(-1)`
The enthalpy change for the reaction `,`
`2overset(*)(C_(2))H_(5) rarr C_(2)H_(6)+C_(2)H_(4)` is `:`

A

`+250kJ mol^(-1)`

B

`+588kJ mol^(-1)`

C

`-252kJ mol^(-1)`

D

`-588kJ mol^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
C

`overset(*)(C_(2))H_(5)+overset(*)(H)rarrC_(2)H_(6),DeltaH=-420kJ mol^(-1)`
`ul( overset(*)(C_(2))H_(5)rarr C_(2)H_(4)+overset(*)(H),DeltaH=168kJ mol^(-1) )`
`:. 2C_(2)H_(5) rarrC_(2)H_(6)+C_(2)H_(4),DeltaH=-252kJ mol^(-1)`
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P BAHADUR-THERMOCHEMISTRY-Exercise 3a objective problems
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  2. If (1)/(2)X(2)O((s)) rarr X((s))+(1)/(4)O(2(g)),DeltaH=90kJ then heat ...

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  3. The data given below are for vapour phase reactions at constant pressu...

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  4. The product of combustion of an aliphatic thiol (RSH) at 298K are :

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  5. The bond energy of H(2) is 104.3 kcal mol^(-1) . If means that :

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  6. Heat of neutralisation of NaOH and HCl is -57.46 kJ // equivalent. The...

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  7. The lattice energy of solid NaCI is 180 kcal mol^(-1). The dissolution...

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  8. Heat of neutralisation of HF is :

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  9. The heat of atomisation of PH(3(g)) is 228kcal mol^(-1) and that of P(...

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  10. Given that : 2CO((g))+O(2(g))rarr2CO(2(g)),DeltaH^(@)=-P kJ C((s))...

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  11. For which reaction DeltaH=DeltaU ?

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  12. The enthalpy of hydrogenation of cyclohexene is -119.5kJ mol^(-1). If ...

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  13. For which of the following reactions heat of formation (Delta(f)H) is ...

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  14. For a hypothetical reaction , 3A rarr A(3) DeltaC(p) (i n J)=6.0+2.0...

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  15. In a flask, colourless N(2)O(4) is in equilibrium with brown-coloured ...

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  16. 1 mol e of ice melts at 0^(@)C and constant pressure of 1 atm by absor...

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  17. Which of the following statement is wrong for C((graph ite))rarr C((d...

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  18. 2 mol es of CO and 1 mol e of O(2) are allowed to react completely to ...

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  19. One mole of a gas is allowed to expand freely in vacuum at 27^(@)C. Th...

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  20. A system is provided 50xx10^(3)J energy and work done on the system is...

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