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For which change DeltaH cancel(=)DeltaU ...

For which change `DeltaH cancel(=)DeltaU` ?

A

`H_(2(g))+(I)_(2(g))hArr2HI_((g))`

B

`HCl_((aq.))+NaOH_((aq.))rarr NaCl_((aq.))+H_(2)O_((l))`

C

`C_((s))+O_(2(g))hArrCO_(2(g))`

D

`N_(2(g))+3H_(2(g)) rarr 2NH_(3(g))`

Text Solution

Verified by Experts

The correct Answer is:
D

`DeltaH=DeltaU+DeltanRT`
for `(a), (b), (c )` Deltan=0` and for `(d) Deltan=-2`
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Chemical reactions are invariably associated with the transfter of energy either in the form of heat or light. In the laboratory, heat changes in physical and chemical processes are measured with an instrument called calorimeter. Heat change in the process is calculated as {:(q = ms DeltaT,,s =Specific heat),(=cDeltaT,,c =Heat capacity):} Heat of reaction at constant volume is measured using bomb calorimeter. q_(V) = DeltaU = Internal energy change Heat of reaction at constant pressure is measured using simple or water calorimeter. q_(p) = DeltaH q_(p) = q_(V) +P DeltaV DeltaH = DeltaU +DeltanRT For which reaction will DeltaH = DeltaU ? Assume each reaction is carried out in an open container.

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P BAHADUR-THERMOCHEMISTRY-Exercise 4 objective Problems
  1. The heat requried to raise the temperature of body by 1^(@)C is called...

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  2. The enthalpy of reaction does not depend upon:

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  3. Calculate enthalpy change of the following reaction : H(2)C=CH(2(g))...

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  4. The enthalpies of combustion of carbon and carbond monoxide are -393.5...

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  5. Consider the reaction, N(2)+3H(2)hArr 2NH(3) carried out at constant...

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  6. If the bond dissociation energies of XY,X(2) and Y(2)( all diatomic mo...

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  7. The standard enthalpy of formation (Delta(f)H^(@)) at 298K for methan...

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  8. The enthalpy change for the following process are listed below: (a) ...

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  9. (Delta H - Delta U) for the formation of carbon monoxide (CO) from its...

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  10. Assuming that water vapour is an ideal gas, the internal energy change...

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  11. Identify the correct statement regarding a spontaneous process :

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  12. In a fuel cell methanol is used as fuel and oxygen gas is used as an o...

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  13. On the basis of the following thermochemical data : (Delta(f)G^(@)H((a...

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  14. For which change DeltaH cancel(=)DeltaU ?

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  15. Molar heat capacity of water in equilibrium with the ice at constant p...

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  16. Standard molar enthalpy of formation of CO(2) is equal to :

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  17. Delta(f)^(@) for CO(2(g)), CO((g)) and H(2)O((g)) are -393.5,-110.5 an...

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  18. Which of the reaction defines Delta(f)H^(@) ?

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  19. Using the data provided, calculate the multiple bond energy (kJ mol^(-...

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  20. The incorrect expression among the following is :

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