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Niobium crystallizes in body-centred cub...

Niobium crystallizes in body-centred cubic structure. If the density is `8.55 g cm^(-3)`, calculate the atomic radius of niobium using its atomic mass `93 u`.

Text Solution

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Atomic mass of `Nb=(Density xx6.023xx10^(23)xxVolume)/(n)`
`(`For `b.c.c.,z=2,` Atomic mass of `Nb=92.90)`
`:. 92.90=(8.55xx6.023xx10^(23)xxV)/(2)`
`:. V=3.6xx10^(-23)cm^(3)`
Now, `V=a^(3)`
`:. a=3sqrt((3.6xx10^(-23)))`
`=3.3xx10^(-8)cm`
For `b.c.c.` structure, `r=(sqrt(3))/(4)a`
`=1.43xx10^(-8)cm`
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