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A solide A^(+)B^(-) has the B^(-) ions a...

A solide `A^(+)B^(-)` has the `B^(-)` ions arranged as below. If the `A^(+)` ions occupy half of the tetrahedral sites in the structure. The formula of solid is `:`

A

`AB`

B

`AB_(2)`

C

`A_(2)B`

D

`A_(3)B_(4)`

Text Solution

Verified by Experts

The correct Answer is:
a

In a closed packed structure, the number of tetrahedral voids per atom of the crystal is two. Since half of the tetrahedral voids are occupied by `A^(+)` , the number of `A^(+)` is same as that of `B^(-)` in the crystal . Thus formula is `AB`.
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