In the fcc arrangement of `A` and `B` atoms whose `A` atoms are at corners of the unit cell and `B` are at the face centres one of the `A` atom is missing from one corner in each unit cell. What is the simplest formula of the compound?
A
`A_(7)B_(3)`
B
`AB_(3)`
C
`A_(7)B_(24)`
D
`A_(7//8)B_(3)`
Text Solution
Verified by Experts
The correct Answer is:
c
No. of atoms of `A` from corners of unit cell `=(7)/(8)` No. atoms of `B` from faces of unit cell `=3` Thus `A:B::(7)/(8):3` or `7:24` Thus formula is `A_(7)B_(24)` Thus formula is `A_(7)B_(24)`.
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