Home
Class 11
CHEMISTRY
A 0.02 M solution of pyridinium hydrochl...

A `0.02 M` solution of pyridinium hydrochloride has `pH=3.44`. Calculate the ionization constant of pyridine.

Text Solution

Verified by Experts

`{:(PyH^(+),+H_(2)OhArr,PyH^(+)OH^(-)+H^(+)),(C(1-h),Ch,Ch):}`
`[H^(+)]=Ch=Csqrt((K_(H))/(C ))=sqrt((C.K_(w))/(K_(b))`
`3.63xx10^(-4)`
`(.: pH=3.44 :. [H^(+)]=3.63xx10^(-4))`
`:. K_(b)=(0.02xx10^(-14))/((3.63xx10^(-4))^(2))=1.52xx10^(-9)`
Promotional Banner

Topper's Solved these Questions

  • IONIC EQUILIBRIUM

    P BAHADUR|Exercise Exercise2|52 Videos
  • IONIC EQUILIBRIUM

    P BAHADUR|Exercise Exercise3A|134 Videos
  • GASEOUS STATE

    P BAHADUR|Exercise Exercise -9|1 Videos
  • MOLE AND EQUIVALENT CONCEPT

    P BAHADUR|Exercise Exercise 9 Advanced numerical problems|61 Videos

Similar Questions

Explore conceptually related problems

A 0.02 M solution of phyridinium hydrochloride has pH=3.44 . Calculate the ionization constant of pyridine.

The pH of 0.1 M solution of cyanic acid (HCNO) is 2.34 . Calculate the ionization constant of the acid its degree of ionisation in the solution.

The pH of 0.1 M solution of an organic acid is 4.0. Calculate its dissociation constant.

It has been found that the pH of a 0.01 M solution of an orginic acid is 4.15 . Calculate the concentration of the anion, the ionization constant of the acid and its pK_(a) .

P BAHADUR-IONIC EQUILIBRIUM-Exercise
  1. A 0.02 M solution of pyridinium hydrochloride has pH=3.44. Calculate t...

    Text Solution

    |

  2. Statement : The dissociation constants of polyrotic acid are in the or...

    Text Solution

    |

  3. Statement: All strong acids in water show almost almost same acidic na...

    Text Solution

    |

  4. Statement: CCI(4),C(6)H(6) and liquid SO(2) are aprotic solvents. Ex...

    Text Solution

    |

  5. Statement: The acidic nature of some cations is: B^(3+)gtBe^(2+)gtNa^(...

    Text Solution

    |

  6. Statement: Acidic nature of boron trihalides is in the order BF(3)ltBC...

    Text Solution

    |

  7. Statement: CO+NaOH overset("High"P)underset("High"T)rarr HCOONa Expl...

    Text Solution

    |

  8. Statement: The dissociation constant of water at 60^(@)C is 10^(-13). ...

    Text Solution

    |

  9. Assertion : Salting out action of sodium soap in presence of NaCl is b...

    Text Solution

    |

  10. Statement: Hydrolysis of salt is an exothermic phenomenon. Explanati...

    Text Solution

    |

  11. Statement: The pH of an aqueous solution of acetic acid remains unchan...

    Text Solution

    |

  12. Statement: In acidic medium, Zn^(2+) is not precipitated by H(2)S. E...

    Text Solution

    |

  13. Statement: Sodium carbonate can be titrated against sulphuric acid by ...

    Text Solution

    |

  14. Statement: In an acid-basic titration involving a strong base and a we...

    Text Solution

    |

  15. Assertion (A): Equivalent conductance increase with dilution for an el...

    Text Solution

    |

  16. Statement: A micture of the solution of a weak acid and its conjugates...

    Text Solution

    |

  17. Statement: For a weak electrolyte, the plot of molar conductivity (Lam...

    Text Solution

    |

  18. Statement: The addition of a small amount of a 'neutral' electrolyte (...

    Text Solution

    |

  19. Statement: In water, orthoboric acid behaves as a weak monobasic acid....

    Text Solution

    |

  20. Prove that degree of dissocation of a weak acid is given by: alpha= ...

    Text Solution

    |

  21. The concentration of fluroacetic acid (K(a)of acid =2.6xx10^(-3)), whi...

    Text Solution

    |