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The equivalent conductance of 1 M benzoi...

The equivalent conductance of `1 M` benzoic acid is `12.8 ohm^(-1) cm^(2)`. If the conductance of benzoate ion and `H^(+)` ion are `12` and `288.42 ohm^(-1) cm^(2)` respectively. Its degree of dissociation is :

A

`39 %`

B

`3.9 %`

C

`0.35 %`

D

`0.039 %`

Text Solution

Verified by Experts

The correct Answer is:
B

`overset(@)(Lambda)(C_(6)H_(5)COOH) = overset(@)(Lambda)(C_(6)H_(5)COO^(-)) + overset(@)(Lambda)_((H^(+)))`
`= 42 xx 288.42 = 330.42`
`alpha = (Lambda_(m)^(C))/(overset(@)(Lambda)_(m)) = (12.8)/(330.42) = 0.0387 = 3.87%`
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