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0.04 N solution of a weak acid has speci...

`0.04 N` solution of a weak acid has specific conductance `4.23 xx 10^(-4) "mho cm"^(-1)`. If the degree of dissociation of acid at this dilution is `0.0612`, then equivalent conductivity at infinite dilution is :

A

`150.8 "mho cm"^(2) eq^(-1)`

B

`172.8 "mho cm"^(2) eq^(-1)`

C

`180.6 "mho cm"^(2) eq^(-1)`

D

`160.9 "mho cm"^(2) eq^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
B

`Lambda_(v) = kappa xx (1000)/(N)`
`= 4.23 xx 10^(-4) xx (1000)/(0.04) = 10.575`
Now `alpha = (Lambda_(v))/(Lambda_(oo))`
`:. (Lambda_(oo)) = (10.575)/(0.0612) = 172.79`
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