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The cell , Zn | Zn^(2+) (1M) || Cu^(2+) ...

The cell , `Zn | Zn^(2+) (1M) || Cu^(2+) (1M) Cu (E_("cell")^@ = 1. 10 V)`,
Was allowed to be completely discharfed at `298 K `. The relative concentration of `2+` to `Cu^(2+) [(Zn^(2=))/(Cu^(2+))]` is :

A

antilog `(24.08)`

B

`3.7.3`

C

`10^(37.3)`

D

`9.65 xx 10^(4)`

Text Solution

Verified by Experts

The correct Answer is:
C

`E_(cell) = E_(cell)^(@) - (0.0591)/(n)log Q`
Where, `Q = ([Zn^(2+)])/([Cu^(2+)])`
For complete discharge `E_(cell) = 0`
So `E_(cell)^(@) = (0.0591)/(2)log'Q = ([Zn^(2+)])/([Cu^(2+)])`
`:. Q = [([Zn^(2+)])/([Cu^(2+)])] = 10^(37.3)`
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