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Electrolusis involves electronation and ...

Electrolusis involves electronation and de-electronation at the redpective electrodes. Anode of electrolytic cell is the electrode at which de-electronation takes place whereas at cathode electronation is noticed. If two or more ions of same charge are to be electronated or de-electronated, the ion having lesser discharge potential is dischargeed. Discharge potential of an ion refers for `E_(OP)^(@)` or `E_(RP)^(@)` as the case may be. The products formed at either electrode is given in terms of Faraday's laws of electrolysis i.e., `w = (Eit)/(96500)`
During electrolysis of `CuSO_(4(aq.))`, the `pH` of solution becomes :

A

`lt 7`

B

`gt 7`

C

`= 7`

D

`ge 7`

Text Solution

Verified by Experts

The correct Answer is:
A

Anode : `2OH^(-) rarr H_(2)O + 1//2O_(2) + 2e,`
Cathode: `Cu^(2+) + 2e rarr Cu`
`[OH^(-)]` decreases, thus `pH` decreases i.e., `lt 7`
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P BAHADUR-ELECTROCHEMISTRY-Exercise (9) ADVANCED NUMERICAL PROBLEMS
  1. Electrolusis involves electronation and de-electronation at the redpec...

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  2. A current of 0.5 A is passed through acidulated water for 30 minute. C...

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  3. A copper cell containing 5% solution of CuSO(4).5H(2)O and a silver ce...

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  4. Some quantity of electricity being used to liberate iodine (at anode) ...

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  5. A test for complete romovel of Cu^(2+) ions form a solution of Cu((aq....

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  6. A Zn rod weighing 25g was kept in 100 mL of 1M CuSO(4) solution. After...

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  7. Assume that impure copper contains only Fe, Au and Ag as impurities. A...

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  8. 50 mL of 0.1 M CuSO(4) solution is electrolysed using Pt electrodes wi...

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  9. An oxide of metal ("at. wt. "= 112) contain 12.5% O(2) by weight. The ...

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  10. 19g fused SnCl(2) was electrolysed using inert electrodes. 0.119g Sn w...

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  11. A lead storage cell is discharged which causes the H(2)SO(4) electroly...

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  12. Two litre solution of a buffer mixture containing 1.0 M NaH(2)PO(4) an...

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  13. A current of 40 microampere is passed through a solution of AgNO(3) fo...

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  14. Suppose a fully charged battery containes 1.50 litre of 5.0 M H(2)SO(4...

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  15. In an analytical determination of aresenic , a solution containing are...

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  16. Assuming that a constant current is delivered, how many kW-h of electr...

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  17. Find the e.m.f. of the following cell at 18^(@)C taking the degree of ...

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  18. If it is disreed to construct the following voltaic cell to have E(cel...

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  19. The e.m.f. of the obtained by combining Zn and Cu electrodes of Danie...

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  20. Calcualte the potential of an indicator electrode versus the standard ...

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  21. An electrode is prepared by dipping a silver strip into a solution sat...

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