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Civen E^@ for Cu^(2+) rarr Cu^+ is + ...

Civen `E^@` for ` Cu^(2+) rarr Cu^+ ` is ` + 0.15 V` and ` Cu^+ rarr Cu ` is ` +0.05 V`
Calculate ` E^@` for ` Cu^(2+) rarr Cu`.

A

`-0.325 V`

B

`+0.325 V`

C

`+0.65 V`

D

`-0.65 V`

Text Solution

Verified by Experts

The correct Answer is:
B
`Cu^(2+) + 2e rarr Cu`
`E_(RP_(Cu))^(@) = + 0.325 V`
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The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . The E^(@) for the reaction : 2Cu^(+) rarr Cu^(2+) + Cu is:

The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . The E^(@) for Cu rarr Cu^(2+) + 2e is :

The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . The E^(@) of Zn|Zn^(2+)||Cu^(2+)|Cu cell is :

The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . The heat of reaction for the change Zn+underset(0.1 M)(Cu^(2+)) hArr underset(1M)(Zn^(2+))+Cu at 27^(@)C is :

The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . Change in entropy for the reaction : Zn+underset(0.1 M)(Cu^(2+)) hArrunderset(1M)(Zn^(2+))+Cu at 27^(@)C is :

The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . The equilibrium constant for the reaction: Zn+Cu^(2+) hArr Zn^(2+)+Cu is:

Goven : (i) CU^(2+) + 2e^- rarr Cu, E^@ = 0.337 V (ii) Cu^(2+) +e^- rarr Cu^(+) , E^2=0.1 5 3 V .

Given: (i) Cu^(2+)+2e^(-) rarr Cu, E^(@) = 0.337 V (ii) Cu^(2+)+e^(-) rarr Cu^(+), E^(@) = 0.153 V Electrode potential, E^(@) for the reaction, Cu^(+)+e^(-) rarr Cu , will be

P BAHADUR-ELECTROCHEMISTRY-Exercise (9) ADVANCED NUMERICAL PROBLEMS
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