Home
Class 12
CHEMISTRY
The E^(@) values for the changes given b...

The `E^(@)` values for the changes given below are measured againest `NHE` at `27^(@)C`.
`Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V`,
`Cu^(+) + e rarr Cu, E^(@) = + 0.50 V`,
`Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V`
The temperature coefficient of emf a cell designed as `Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu` is `-1.4 xx 10^(-4)V` per degree. For a cell reaction in equilibrium `DeltaG = 0` and `DeltaG^(@) = -2.303 RTlog_(10)K_(c)`. The heat of reaction and entropy change during the reaction are are related by `DeltaG = DeltaH - TDeltaS`.
The equilibrium constant for the disproportionation of `Cu^(+)` is:

A

`8.5 xx 10^(-5)`

B

`8.5 xx 10^(5)`

C

`8.5 xx 10^(-4)`

D

`8.5 xx 10^(6)`

Text Solution

Verified by Experts

The correct Answer is:
B
`E^(@) = (0.059)/(1)logK_(c)` or `0.35 = (0.059)/(1)logK_(c)`
`:. K_(c) = 8.5 xx 10^(5)`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    P BAHADUR|Exercise (A) ELECTROLYSIS|2 Videos

  • ELECTROCHEMISTRY

    P BAHADUR|Exercise (B) ELECTRODE POTENTIAL AND EMF|1 Videos

  • DILUTE SOLUTION AND COLLIGATIVE PROPERTIES

    P BAHADUR|Exercise Exercise 9 Advanced Numerical|12 Videos

  • MOCK TEST PAPER

    P BAHADUR|Exercise Exercise|92 Videos

Similar Questions

Explore conceptually related problems

The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . The E^(@) for Cu rarr Cu^(2+) + 2e is :

The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . The equilibrium constant for the reaction: Zn+Cu^(2+) hArr Zn^(2+)+Cu is:

The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . The E^(@) of Zn|Zn^(2+)||Cu^(2+)|Cu cell is :

The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . The E^(@) for the reaction : 2Cu^(+) rarr Cu^(2+) + Cu is:

The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . The heat of reaction for the change Zn+underset(0.1 M)(Cu^(2+)) hArr underset(1M)(Zn^(2+))+Cu at 27^(@)C is :

The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . Change in entropy for the reaction : Zn+underset(0.1 M)(Cu^(2+)) hArrunderset(1M)(Zn^(2+))+Cu at 27^(@)C is :

The E^(@) values for the changes given below are measured againest NHE at 27^(@)C . Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V , Cu^(+) + e rarr Cu, E^(@) = + 0.50 V , Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V The temperature coefficient of emf a cell designed as Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu is -1.4 xx 10^(-4)V per degree. For a cell reaction in equilibrium DeltaG = 0 and DeltaG^(@) = -2.303 RTlog_(10)K_(c) . The heat of reaction and entropy change during the reaction are are related by DeltaG = DeltaH - TDeltaS . If 9.65 ampere current is passed through making Cu anode Zn cathode for 1000 sec in the cell Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu , the e.m.f. of cell after after passage of current would be :

Goven : (i) CU^(2+) + 2e^- rarr Cu, E^@ = 0.337 V (ii) Cu^(2+) +e^- rarr Cu^(+) , E^2=0.1 5 3 V .

Civen E^@ for Cu^(2+) rarr Cu^+ is + 0.15 V and Cu^+ rarr Cu is +0.05 V Calculate E^@ for Cu^(2+) rarr Cu .

Given: (i) Cu^(2+)+2e^(-) rarr Cu, E^(@) = 0.337 V (ii) Cu^(2+)+e^(-) rarr Cu^(+), E^(@) = 0.153 V Electrode potential, E^(@) for the reaction, Cu^(+)+e^(-) rarr Cu , will be

P BAHADUR-ELECTROCHEMISTRY-Exercise (9) ADVANCED NUMERICAL PROBLEMS
  1. The E^(@) values for the changes given below are measured againest NH...

    Text Solution

    |

  2. A current of 0.5 A is passed through acidulated water for 30 minute. C...

    Text Solution

    |

  3. A copper cell containing 5% solution of CuSO(4).5H(2)O and a silver ce...

    Text Solution

    |

  4. Some quantity of electricity being used to liberate iodine (at anode) ...

    Text Solution

    |

  5. A test for complete romovel of Cu^(2+) ions form a solution of Cu((aq....

    Text Solution

    |

  6. A Zn rod weighing 25g was kept in 100 mL of 1M CuSO(4) solution. After...

    Text Solution

    |

  7. Assume that impure copper contains only Fe, Au and Ag as impurities. A...

    Text Solution

    |

  8. 50 mL of 0.1 M CuSO(4) solution is electrolysed using Pt electrodes wi...

    Text Solution

    |

  9. An oxide of metal ("at. wt. "= 112) contain 12.5% O(2) by weight. The ...

    Text Solution

    |

  10. 19g fused SnCl(2) was electrolysed using inert electrodes. 0.119g Sn w...

    Text Solution

    |

  11. A lead storage cell is discharged which causes the H(2)SO(4) electroly...

    Text Solution

    |

  12. Two litre solution of a buffer mixture containing 1.0 M NaH(2)PO(4) an...

    Text Solution

    |

  13. A current of 40 microampere is passed through a solution of AgNO(3) fo...

    Text Solution

    |

  14. Suppose a fully charged battery containes 1.50 litre of 5.0 M H(2)SO(4...

    Text Solution

    |

  15. In an analytical determination of aresenic , a solution containing are...

    Text Solution

    |

  16. Assuming that a constant current is delivered, how many kW-h of electr...

    Text Solution

    |

  17. Find the e.m.f. of the following cell at 18^(@)C taking the degree of ...

    Text Solution

    |

  18. If it is disreed to construct the following voltaic cell to have E(cel...

    Text Solution

    |

  19. The e.m.f. of the obtained by combining Zn and Cu electrodes of Danie...

    Text Solution

    |

  20. Calcualte the potential of an indicator electrode versus the standard ...

    Text Solution

    |

  21. An electrode is prepared by dipping a silver strip into a solution sat...

    Text Solution

    |