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A test for complete romovel of Cu^(2+) i...

A test for complete romovel of `Cu^(2+)` ions form a solution of `Cu_((aq.))^(2+)` is to add `NH_(3(aq.))`. A buke colour signifies the fomaltionn of complex `[Cu(NH_(3))_(4)]^(2+)` having `K_(f) = 1.1 xx 10^(13)` and thus confirms the presence of `Cu^(2+)` in solution. `250 mL` of `0.1 M CuSO_(4(aq.))` is electrolysed by passing a current of `3.512` ampere for `1368` second. After passage of this passage of this charge sufficient quantity of `NH_(3(aq.))` is added to electrolysed solution maintaining `[NH_(3)] = 0.10 M`. If `[Cu(NH_(3))_(4)]^(2+)` is detectable up to its concentration as low as `1 xx 10^(-5)`, would a blue colour be shown by the electrolysed solution on addition of `NH_(3)`.

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A test for complete removal of Cu^(2+) ions from a solution of Cu^(2+) (aq) is to add NH_3 (aq). A blue colour signifies the formation of complex [Cu(NH_3)_4]^(2+) having K_f = 1.1 xx 10^13 and thus confirms the presence of Cu^(2+) in solution. 250 mL of 0.1 M CuSO_4 (aq.) is electrolysed by passing a current of 3.512 ampere for 1368 second. After passage of this charge sufficient quantity of NH_3 (aq) is added to electrolysed solution maintianing [NH_3] = 0.10 M. If [Cu(NH_3)_4]^(2+) is detectable upto its concentration as low as 1 xx 10^(–5) , would a blue colour be shown by the electrolysed solution on addition of NH_3 ?

The complex ion [Cu(NH_(3))_(4)]^(2+) has

The complex ion [Cu(NH_3)_4]^(2+) is

The solution of the complex [Cu(NH_(3))_(4)]SO_(4) in water will

When excess of NH_(3) (aq) is added to a blue solution containing Cu_((aq))^(2+) ions

CuSO_(4)+NH_(3)(excess) to [Cu(NH_(3))_(4)]^(2+)

P BAHADUR-ELECTROCHEMISTRY-Exercise (9) ADVANCED NUMERICAL PROBLEMS
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