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Calculate the degree of hydrolysis and h...

Calculate the degree of hydrolysis and hydrolysis constant of `M//32` solution of aniline hydrochloride from the following cell data.
`{:Pt:}|{:(H_(2)),(1atm):}|{:(H^(+)),(1M):}||{:(M)/(32)C_(6)H_(5)NH_(3)^(+)Cl_((aq.))^(-):}|{:(H_(2)),(1atm):}|Pt,`
`E_(cell) = -0.188 V`

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Verified by Experts

The correct Answer is:
`2.08 xx 10^(-2), 1.352 xx 10^(-5) ;`
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Determine the degree of hydrolysis and hydrolysis constant of aniline hydrochloride in M//32 solution of salt at 298K from the following cell data at 298K . Pt|H_(2)(1atm)|H^(+) (1M)||M//32 C_(6)H_(5)NH_(3)CI |H_(2)(1atm)|Pt, E_(cell) = -0.188V .

The pH of LHE in the following cell is : Pt, H_(2)(1atm)|H^(o+)(x M)||H^(o+)(0.1M)|H_(2)(0.1atm)Pt E_(cell)=0.295V .

Calculated E_("cell") for the cell will be: P_(t)|(H_(2_((g)))),(1 "atm")||(1N KOH_((aq))),(prop = 75%)||((N)/(10)HCl_((aq))),(prop = 90%)||(H_(2_((g)))),(atm)|Pt

pH of the anodic solution of the following cell is Pt, H_2(1atm)|H^+(xM)||H^(+)(1M)|H_2(1 atm ),Pt if E_("cell") =0.2364V.

The cell reaction for the given cell is spontaneous if: Pt,H_(2) (P_(1) atm)| H^(+) (1M)| H_(2) (P_(2) atm), Pt

Calculate the pH of the following half cells solutions and also the molarity of acids: {: (Pt_(H_(2))),(atm):}|{:H_(2)SO_(4):} " " E = 0.05 (b) {: (Pt_(H_(2))),(atm):}|{:HCl:} " " E = 0.1 V

Calculate pH of the half cell : Pt,H_(2)(1 atm)|H_(2)SO_(4)" "E^(c-)=-0.3V

Construct a labelled diagram for the following cell- Zn|Zn^(2+)(1M)||H^(+)(1M)|H_(2(g. 1"atm"))|pt

P BAHADUR-ELECTROCHEMISTRY-Exercise (9) ADVANCED NUMERICAL PROBLEMS
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  5. Calculate the minimum weight of NaOH required to be added in R.H.S. t...

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  6. Consider the cell Ag|AgBr((s)), Br^(-)||AgCl((s)), Cl^(-)|Ag at 25^(@)...

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  7. Calculate the half cell potential of a reaction Ag(2)S + 2e rarr 2Ag +...

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  8. The standard electrode potential are for the following reactions : F...

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  10. The e.m.f. of cell Zn|ZnSO(4)||CuSO(4)|Cu at 25^(@)C lis 0.03 V and th...

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  11. For the cell Mg((s))|Mg((aq.))^(2+)||Ag((aq.))^(+)|Ag((s)), calculate ...

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  12. The standard reduction potential of E(Bi^(3+)//Bi)^(@) and E(Cu^(2+)//...

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  13. Show that the potentials are additive for the process in which half re...

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  14. An alloy weighing 1.05g of Pb-Ag was dissolved in desired amount of HN...

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  15. The following galvanic cell was Zn|{:(Zn(NO(3))(2(aq.))),(100 mL"," ...

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  16. When silver chloride is dissolved in a large excess of ammonia, practi...

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  17. Estimate the cell potential of a Daniel cell having 1.0 M Zn^(2+) and ...

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  18. Calculate the e.m.f. of cell {:(Pt(H(2))),(1atm):}|{:(CH(3)COOH),(0....

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  19. Calculate the degree of hydrolysis and hydrolysis constant of M//32 so...

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  20. Design the cell having one of the half reaction CuS + 2e rarr Cu + S^(...

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