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The potential of a silver// silver chlor...

The potential of a silver`//` silver chloride electrode measured with respect to a saturated calomel electrode `(E_(OP)^(@)=0.244 V)` is `0.022 V`. The standard reduction potential of silver`//`silver chloride electrode is:

A

`0.222 V`

B

`0.266 V`

C

`-0.222V`

D

`-0.266 V`

Text Solution

Verified by Experts

`E_(cell)^(@)=E_(OP_("Calomel"))+E_(RP_(Ag//AgCl))^(@)`
`-0.002=-0.244+(E_(RP_(Ag//AgCl))^(@))`
`:. (E_(RP_(Ag//AgCl))^(@))=0.244-0.022=0.22 V`
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