Home
Class 12
CHEMISTRY
(i) An aqueous solution of a white colou...

(i) An aqueous solution of a white coloured compound `(A)` on reaction with `HCl` gives a white precipitate of compound `(B)`.
(ii) `(B)` becomes soluble in chlorine water with the formation of `(C)`
(iii) `(C)` reacts with `KI` to give a precipitate which becomes solube in excess of it forming a compount `(D)`. the compound `(D)` is used for detecting ammonium salts.
(iv) `(B)` and `(C)` both, on treatement with `SnCl_(2)` give a grey precipitate of `(E)`.
(v) When conc. `H_(2)SO_(4)` is added slowly into a mixture of cold solutions of `(A)` and `FeSO_(4)` is added slowly into a mixture of cold solutions of `(A)` and `FeSO_(4)`, a brown ring of compound `(F)` is formed.
Compound `(A)` contains ... ions.

A

`Pb^(2+),NO_(3)^(-)`

B

`Hg^(2+)m,NO_(3)^(-)`

C

`Hg_(2)^(2+),NO_(3)^(-)`

D

`Hg^(2+),Cl^(-)`

Text Solution

Verified by Experts

`{:((i),underset((A))(Hg_(2)(NO_(3))_(2))+2HCl tounderset((B))(Hg_(2)Cl_(2))+2HNO_(3)),((ii),Hg_(2)Cl_(2)+Cl_(2)tounderset((C))(2HgCl_(2))" (soluble)"),((iii),HgCl_(2)+2KIto2KCl+HgI_(2)(ppt)),(,HgI_(2)+2KItounderset("used for test of "NH_(3),"Nessler's reagent")underset((D))(K_(2)HgI_(4))),((iv),underset((B))(Hg_(2)Cl_(2))+SnCl_(2)toSnCl_(4)+underset((E)grey)(Hg_(2))),(,2HgCl_(2)+2SnCl_(2)to2SnCl_(4)+underset((E))(Hg_(2))),((v),Hg_(2)(NO_(3))_(2)+2H_(2)SO_(4)to2HgHSO_(4)+2HNO_(3)),(,6FeSO_(4)+2HNO_(3)+3H_(2)SO_(4)to3Fe_(2)(SO_(4))_(3)+4H_(2)O+2NO),(,FesO_(4)+NOtounderset((F)"Brown ring")(FeSO_(4).NO)):}`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    P BAHADUR|Exercise Exercise (9) ADVANCED NUMERICAL PROBLEMS|36 Videos
  • SOLID STATE

    P BAHADUR|Exercise Exercise 9|1 Videos

Similar Questions

Explore conceptually related problems

(i) An aqueous solution of a white coloured compound (A) on reaction with HCl gives a white precipitate of compound (B) . (ii) (B) becomes soluble in chlorine water with the formation of (C) (iii) (C) reacts with KI to give a precipitate which becomes solube in excess of it forming a compount (D) . the compound (D) is used for detecting ammonium salts. (iv) (B) and (C) both, on treatement with SnCl_(2) give a grey precipitate of (E) . (v) When conc. H_(2)SO_(4) is added slowly into a mixture of cold solutions of (A) and FeSO_(4) is added slowly into a mixture of cold solutions of (A) and FeSO_(4) , a brown ring of compound (F) is formed. Grey precipitate of (E) is :

(i) An aqueous solution of a white coloured compound (A) on reaction with HCl gives a white precipitate of compound (B) . (ii) (B) becomes soluble in chlorine water with the formation of (C) (iii) (C) reacts with KI to give a precipitate which becomes solube in excess of it forming a compount (D) . the compound (D) is used for detecting ammonium salts. (iv) (B) and (C) both, on treatement with SnCl_(2) give a grey precipitate of (E) . (v) When conc. H_(2)SO_(4) is added slowly into a mixture of cold solutions of (A) and FeSO_(4) is added slowly into a mixture of cold solutions of (A) and FeSO_(4) , a brown ring of compound (F) is formed. The oxidation number of FE in compound (F) is:

(i) An aqueous solution of a white coloured compound (A) on reaction with HCl gives a white precipitate of compound (B) . (ii) (B) becomes soluble in chlorine water with the formation of (C) (iii) (C) reacts with KI to give a precipitate which becomes solube in excess of it forming a compount (D) . the compound (D) is used for detecting ammonium salts. (iv) (B) and (C) both, on treatement with SnCl_(2) give a grey precipitate of (E) . (v) When conc. H_(2)SO_(4) is added slowly into a mixture of cold solutions of (A) and FeSO_(4) is added slowly into a mixture of cold solutions of (A) and FeSO_(4) , a brown ring of compound (F) is formed. (A) on dissociation in H_(2)SO_(4) gives:

A binary of potassium (A) on heating with sulphar, compound (B) is formed. (B) on reacting with BaCI_(2) gives a white precipitate (C ) which is insoluble in concentrated HCI. Indenfity (A), (B) and (C ).

Zinc on reaction with NaOH gives a salt (A) alongwith a gas (B). (A) on reaction with H_(2)S gas gives a white precipitate (C ). Identify (A), (B) and (C ).

An aqueous solution of compound 'A' gives white precipitate with 2M HCl .The precipitate becomes black on addition of aqueous NH_(3) due to formation of 'B' . 'B' dissolves in aquaregia. 'A' and 'B' are:

An aqueous solution of a salt (A) gives a white precipitate (B) with sodium chloride solution. The filtrate gives a black precipitate (C ) when H_(2)S is passed into it. Compound (B) dissolves in hot water and the solution gives a yellow precipitate (D) on treatment with sodium iodide. The compound (A) does gas on heating. Identify the compounds (A) to (D). Compound C is :

An aqueous solution of a salt (A) gives a white precipitate (B) with sodium chloride solution. The filtrate gives a black precipitate (C ) when H_(2)S is passed into it. Compound (B) dissolves in hot water and the solution gives a yellow precipitate (D) on treatment with sodium iodide. The compound (A) does gas on heating. Identify the compounds (A) to (D). Compound B is :

P BAHADUR-MOCK TEST PAPER-Exercise
  1. Statement-1:Compounds having -NR(3)^(+),-SR(3)^(+) etc. as leaving gro...

    Text Solution

    |

  2. Statement-1: CF(3)-CHCl(2) when treated with C(2)H(5)OD, the major pro...

    Text Solution

    |

  3. (i) An aqueous solution of a white coloured compound (A) on reaction w...

    Text Solution

    |

  4. (i) An aqueous solution of a white coloured compound (A) on reaction w...

    Text Solution

    |

  5. (i) An aqueous solution of a white coloured compound (A) on reaction w...

    Text Solution

    |

  6. (i) An aqueous solution of a white coloured compound (A) on reaction w...

    Text Solution

    |

  7. (i) An aqueous solution of a white coloured compound (A) on reaction w...

    Text Solution

    |

  8. (i) An aqueous solution of a white coloured compound (A) on reaction w...

    Text Solution

    |

  9. (i) An aqueous solution of a white coloured compound (A) on reaction w...

    Text Solution

    |

  10. The cell designed as Pt(H(2))|HCl(aq)||Hg(2)Cl(2),0.01 N KCl|Hg has em...

    Text Solution

    |

  11. The cell designed as Pt(H(2))|HCl(aq)||Hg(2)Cl(2),0.01 N KCl|Hg has em...

    Text Solution

    |

  12. The cell designed as Pt(H(2))|HCl(aq)||Hg(2)Cl(2),0.01 N KCl|Hg has em...

    Text Solution

    |

  13. The cell designed as Pt(H(2))|HCl(aq)||Hg(2)Cl(2),0.01 N KCl|Hg has em...

    Text Solution

    |

  14. The cell designed as Pt(H(2))|HCl(aq)||Hg(2)Cl(2),0.01 N KCl|Hg has em...

    Text Solution

    |

  15. The cell designed as Pt(H(2))|HCl(aq)||Hg(2)Cl(2),0.01 N KCl|Hg has em...

    Text Solution

    |

  16. Which of the following reaction will not give picric acid?

    Text Solution

    |

  17. In CH(3)-underset(..)(O)-CH(3), oxygen atom has p^(3) hybridisation wi...

    Text Solution

    |

  18. Which of the following process may be reversible?

    Text Solution

    |

  19. Which statement is correct ?

    Text Solution

    |

  20. The molecule has:

    Text Solution

    |