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Ten mole of hydrogen at N.T.P is compres...

Ten mole of hydrogen at `N.T.P` is compressed adiabatically so that it temperature becomes `400^(@)C`. How much work is done on the gas? Also, Calculate the increase in internal energy of the gas. Take `R=8.4J mol e^(-1)K^(-1) and gamma= 1.4`.

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To solve the problem step by step, we will calculate the work done on the gas during the adiabatic compression and the increase in internal energy of the gas. ### Step 1: Identify the given values - Number of moles, \( N = 10 \, \text{moles} \) - Initial temperature at NTP, \( T_1 = 0^\circ C = 273 \, \text{K} \) - Final temperature, \( T_2 = 400^\circ C = 673 \, \text{K} \) - Gas constant, \( R = 8.4 \, \text{J mol}^{-1} \text{K}^{-1} \) - Heat capacity ratio, \( \gamma = 1.4 \) ### Step 2: Calculate the work done on the gas during adiabatic compression The formula for work done on an ideal gas during an adiabatic process is given by: \[ W = \frac{N R}{1 - \gamma} (T_2 - T_1) \] Substituting the values into the formula: \[ W = \frac{10 \, \text{moles} \times 8.4 \, \text{J mol}^{-1} \text{K}^{-1}}{1 - 1.4} (673 \, \text{K} - 273 \, \text{K}) \] Calculating \( T_2 - T_1 \): \[ T_2 - T_1 = 673 \, \text{K} - 273 \, \text{K} = 400 \, \text{K} \] Now substituting this back into the work formula: \[ W = \frac{10 \times 8.4}{1 - 1.4} \times 400 \] Calculating \( 1 - 1.4 = -0.4 \): \[ W = \frac{10 \times 8.4}{-0.4} \times 400 \] Calculating \( \frac{10 \times 8.4}{-0.4} = -210 \): \[ W = -210 \times 400 = -84000 \, \text{J} \] Thus, the work done on the gas is: \[ W = -84000 \, \text{J} \quad \text{(or } -8.4 \times 10^4 \, \text{J)} \] ### Step 3: Calculate the increase in internal energy of the gas In an adiabatic process, the first law of thermodynamics states: \[ dQ = dU + dW \] Since \( dQ = 0 \) for an adiabatic process, we have: \[ dU = -dW \] Substituting the value of \( dW \): \[ dU = -(-84000 \, \text{J}) = 84000 \, \text{J} \] Thus, the increase in internal energy of the gas is: \[ dU = 84000 \, \text{J} \quad \text{(or } 8.4 \times 10^4 \, \text{J)} \] ### Final Results - Work done on the gas: \( W = -84000 \, \text{J} \) - Increase in internal energy: \( dU = 84000 \, \text{J} \)
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