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Given is the graph between (PV)/T and P ...

Given is the graph between `(PV)/T` and P for 1 gm of oxygen gas at two different temperatures `T_(1) and T_(2)` Fig. Given, density of oxygen `= 1.427 kg m^(-3)`. The value of `(PV)//(T)` at the point A and the relation between `T_(1) and T_(2)` are respectively :

A

`0.256 JK^(-1) and T_(1) lt T(2)`

B

`8.314 mol^(-1) K^(-1) and T_(1) gt T(2)`

C

`0.256 JK^(-1) and T_(1) gt T(2)`

D

`4.28 JK^(-1) and T_(1) lt T(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

`PV = nRT = m/M RT`
Where m = mass of the gas
and `m/M = n =` number of moles
`(PV)/(T) = nR = a` constant for all value of P.
That is why, ideally it is a straight line.
`:. (PV)/T = (1 gm)/(32 gm) xx 8.31 J "mole"^(-1) K^(-1)`
`= 0.256 JK^(-1)`. Also, `T_(1) gt T_(2)`.
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