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Which of the following has the highest m...

Which of the following has the highest melting point ?

A

NaCl

B

NaF

C

NaBr

D

NaI

Text Solution

Verified by Experts

The correct Answer is:
B
NaF due to its largest lattice energy has the highest melting point.
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According to Fajans'rules, the percentage of covalent character in an ionic compound increase if the cation is highly charged or small in size and the anion is large or cation has pseudoinert gas configuration. As a result of the increased covalent character, solubility in less polar solvent increases and the melting point decreases. Which of the following has highest melting point?

MARVEL PUBLICATION-S BLOCK ELEMENTS -TEST YOUR GRASP
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  5. Which of the following is sparingly soluble in water ?

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  6. Which of the following statement is incorrect ? a)Oxide of aluminium ...

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  7. Pick out statement (s) which is/are not true about diagonal relationsh...

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  8. Which one is the highest melting halide ?

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  9. "Electron" is an alloy of

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  10. Sodium burns in dry air to give

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  11. Select odd pair of name of chemical and its chemical composition.

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  12. The raw materials required for the manufacture of Na(2)CO(3) by Solva...

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  13. The carbonate that will not decompose on heating is

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  14. The alkali metal used in photoelectric cell is

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  15. Which of the following if good source of potassium ?

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  16. The first ionization enthalpy of magnesium is lower than the first ion...

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  17. Which of the following feact only with boiling water ?

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  18. Mg burns in air to give

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  19. Beryllium and aluminium exhibit many properties which are similar . Bu...

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  20. Which of the following is not a compound of calcium ?

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  21. Mark the compound which does not contain calcium carbonate ?

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