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The equivalent weight of MnSO(4) is half...

The equivalent weight of `MnSO_(4)` is half its molecular weight when it is converted to

A

(a)`Mn_(2)O_(3)`

B

(b)`MnO_(2)`

C

(c )`MnO_(4)^(-)`

D

(d)`MnO_(4)^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
B

Equivalent `"weight"=("molecular weight")/("valency factor")`
If valency is 2, then equivalent weight will be equal to its molecular weight.
In `MnSO_(4)`, the oxidation state of Mn is +II
In `Mn_(2)O_(3)`, the oxidation state of Mn is +III
In `MnO_(2)`, the oxidation state of Mn is +IV
In `MNO_(4)`, the oxidation state of Mn is +VII
In `Mn_(4)^(2-)`, the oxidation state of Mn is +VI
Thus, when `MnSO_(4)` is converted into `MnO_(2)`, then the valency factor is 2, and the equivalent weight of `MnSO_(4)` will be half of its molecular weight.
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