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In the neutralization of Na(2)S(2)O(3) u...

In the neutralization of `Na_(2)S_(2)O_(3)` using `K_(2)Cr_(2)O_(7)` by idometry, the equivalent weight of `K_(2)Cr_(2)O_(7)` is

A

(a)`"molecular weight"//2`

B

(b)`"molecular weight"//6`

C

(c )`"molecular weight"//3`

D

(d)same as molecular weight

Text Solution

Verified by Experts

The correct Answer is:
B

In this reaction
`Cr_(2)O_(3)^(2-)` is changed into `Cr_(3)^(3+)` ion.
So, equivalent weight of
`K_(2)Cr_(2)O_(7)=("molecular wt".)/("decrease of oxidation number"xxn)`
`("where n= No. of atoms of" Cr)`
`=("molecular wt".)/(3xx2)=("molecular wt.")/6`
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