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In the reaction 2CuSO(4)+4KI rarr 2Cu(...

In the reaction
`2CuSO_(4)+4KI rarr 2Cu_(2)I_(2)+I_(2)+2K_(2)SO_(4)` the equivalent weight of `CuSO_(4)` will be:

A

(a)`79.75`

B

(b)`159.5`

C

(c )`329`

D

(d)None of these

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To find the equivalent weight of \( \text{CuSO}_4 \) in the given reaction: \[ 2\text{CuSO}_4 + 4\text{KI} \rightarrow 2\text{Cu}_2\text{I}_2 + \text{I}_2 + 2\text{K}_2\text{SO}_4 \] we will follow these steps: ### Step 1: Identify the change in oxidation state In the reaction, copper in \( \text{CuSO}_4 \) changes from an oxidation state of +2 (in \( \text{CuSO}_4 \)) to +1 (in \( \text{Cu}_2\text{I}_2 \)). ### Step 2: Determine the change in oxidation number The change in oxidation number for copper is: \[ \text{Cu}^{2+} \rightarrow \text{Cu}^{+} \] This represents a change of: \[ 2 - 1 = 1 \] ### Step 3: Calculate the n-factor The n-factor is defined as the total change in oxidation number per formula unit of the compound. Since one copper atom changes its oxidation state by 1, the n-factor for \( \text{CuSO}_4 \) is 1. ### Step 4: Calculate the molecular weight of \( \text{CuSO}_4 \) The molecular weight of \( \text{CuSO}_4 \) can be calculated as follows: - Atomic weight of Copper (Cu) = 63.5 g/mol - Atomic weight of Sulfur (S) = 32 g/mol - Atomic weight of Oxygen (O) = 16 g/mol Thus, the molecular weight of \( \text{CuSO}_4 \) is: \[ \text{Molecular weight} = 63.5 + 32 + (4 \times 16) = 63.5 + 32 + 64 = 159.5 \, \text{g/mol} \] ### Step 5: Calculate the equivalent weight The equivalent weight is given by the formula: \[ \text{Equivalent weight} = \frac{\text{Molecular weight}}{\text{n-factor}} \] Substituting the values we have: \[ \text{Equivalent weight} = \frac{159.5}{1} = 159.5 \, \text{g/equiv} \] ### Conclusion The equivalent weight of \( \text{CuSO}_4 \) is 159.5 g/equiv.

To find the equivalent weight of \( \text{CuSO}_4 \) in the given reaction: \[ 2\text{CuSO}_4 + 4\text{KI} \rightarrow 2\text{Cu}_2\text{I}_2 + \text{I}_2 + 2\text{K}_2\text{SO}_4 \] we will follow these steps: ...
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Direct titration of I_(2) with a reducing agent is called iodimetry. If I_(2) is leberated by the oxidation of I_(ɵ) ion by a strong oxidising agent in neutral or acidic medium, the liberated I_(2) is then titrated with reducing agent. Iodometry is used to estimate the strngth of the oxidising agent. For example, in the estimation of Cu^(2+) with S_(2)O_(3)^(2-) Cu^(2+)+I^(ɵ)toCuI_(2)+I_(2) (iodometry) I_(2)+S_(2)O_(3)^(2-)toS_(4)O_(6)^(2-)+I^(ɵ) (iodimetry) Strach is used as an indicator at the end point, which forms bluecoloured complex with I_(3)^(ɵ) Disappearance of blue colourindicates the end point whe free I_(2) in not present. Q. In the reaction 2CuSO_(4)+4KItoCu_(2)I_(2)+2K_(2)SO_(4)+I_(2) The equivalent weight of CuSO_(4) is (Mw=159.5g mol^(-1))

2KI+CuSO_(4) to CuI darr+(1)/(2)I_(2)+K_(2)SO_(4)

CuSO_(4)+2KI to CuI darr+(1)/(2)I_(2)+K_(2)SO_(4)

Cu_(2)S+MnO_(4)^(ө)rarrCu^(2+)+Mn^(2+)+SO_(2) The equivalent weight of Cu_(2) is

CuSO_(4)+2KCN to CuCN darr+(CN)_(2)uarr+K_(2)SO_(4)

A2Z-SOME BASIC CONCEPTS OF CHEMISTRY-Redox Titration And Stoichiometry In Various Types Of Reaction
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