Home
Class 11
CHEMISTRY
Bohr model cannot explain spectrum of...

Bohr model cannot explain spectrum of

A

the hydrogen atom only

B

all elements

C

any atomic or ionic species having one electron only

D

the hydrogen molecule

Text Solution

AI Generated Solution

The correct Answer is:
**Step-by-Step Solution:** 1. **Understanding the Bohr Model**: The Bohr model of the atom was proposed by Niels Bohr in 1913. It describes the atom as a small, positively charged nucleus surrounded by electrons that travel in circular orbits around the nucleus. The model was primarily developed to explain the spectrum of the hydrogen atom. 2. **Limitations of the Bohr Model**: The Bohr model is effective for hydrogen because it has only one electron. However, it has limitations when applied to multi-electron atoms or ions. The model does not take into account electron-electron interactions, which become significant in atoms with more than one electron. 3. **Spectra of Multi-Electron Atoms**: For atoms with more than one electron, the energy levels are affected by the presence of other electrons. This leads to complexities in the spectral lines that cannot be accurately predicted by the Bohr model. 4. **Conclusion**: Therefore, the Bohr model cannot explain the spectrum of multi-electron species (such as helium, lithium, etc.) or more complex atoms. It is only applicable to hydrogen-like atoms, which have a single electron. **Final Answer**: The Bohr model cannot explain the spectrum of multi-electron atoms. ---

**Step-by-Step Solution:** 1. **Understanding the Bohr Model**: The Bohr model of the atom was proposed by Niels Bohr in 1913. It describes the atom as a small, positively charged nucleus surrounded by electrons that travel in circular orbits around the nucleus. The model was primarily developed to explain the spectrum of the hydrogen atom. 2. **Limitations of the Bohr Model**: The Bohr model is effective for hydrogen because it has only one electron. However, it has limitations when applied to multi-electron atoms or ions. The model does not take into account electron-electron interactions, which become significant in atoms with more than one electron. 3. **Spectra of Multi-Electron Atoms**: For atoms with more than one electron, the energy levels are affected by the presence of other electrons. This leads to complexities in the spectral lines that cannot be accurately predicted by the Bohr model. ...
Promotional Banner

Topper's Solved these Questions

  • ATOMIC STRUCTURE

    A2Z|Exercise Hydrogen Spectrum|35 Videos
  • ATOMIC STRUCTURE

    A2Z|Exercise Heisenbergs Uncertainity Principle And Debroglie Equation|44 Videos
  • ATOMIC STRUCTURE

    A2Z|Exercise Electromagnetic Wave Theory, Plank Quantum Theory And Photoelectric Effect|25 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

Bohr's model cannot explain the spectrum of neutral Lithium atoms because

Bohr's model can explain

Bohr's atomic model can expalin the spectrum of

Bohr's Model

Bohr's Model

Bohr's model of atom can explain the spectrum of all except de-Broglie's And Heisenberg Uncertainity Principle

Given below are two statements : Statement I : Rutherfods's gold foil experiment cannot explain the line spectrum of hydrogen atom. Statement II : Bohr's model of hydrogen atom contradicts Heisenberg's uncertainity principle. In the light of the above statements, choose the most appropriate answr from the options given below :

A2Z-ATOMIC STRUCTURE-Bohr'S Model
  1. The radius of which of the following orbit is same as that of the firs...

    Text Solution

    |

  2. The ionisation enthalpy of hydrogen atom is 1.312xx10^(6)J*mol^(-1). T...

    Text Solution

    |

  3. Bohr model cannot explain spectrum of

    Text Solution

    |

  4. Which statement is wrong about Bohr's theory

    Text Solution

    |

  5. The first five ionization energies of an element are 801,2428,3660,250...

    Text Solution

    |

  6. The kinetic energy of an electron in the second Bohr orbit of a hydrog...

    Text Solution

    |

  7. Which statement is true.

    Text Solution

    |

  8. The first four ionization energies of an element are 191, 578, 872, an...

    Text Solution

    |

  9. If velocity of an electron in 1^(st) Bohr orbit of hydrogen atom us x,...

    Text Solution

    |

  10. Energy of an electron is given by E = - 2.178 xx 10^-18 J ((Z^2)/(n^2)...

    Text Solution

    |

  11. The ratio of the velocity of light and the velocity of electron in the...

    Text Solution

    |

  12. The wavelength associated with an electron moving with a velocity of 1...

    Text Solution

    |

  13. The energy of electron in first Bohr's orbit of H-"atom" is - 13.6 eV ...

    Text Solution

    |

  14. Ionisation energy of He^+ is 19.6 xx 10^-18 J "atom"^(-1). The energy ...

    Text Solution

    |

  15. The energy of second orbit of hydrogen is equal to the energy of ,

    Text Solution

    |

  16. If first ionisation energy of hydrogen be E, then the ionisation energ...

    Text Solution

    |

  17. The ratio of (E2 - E1) "to" (E4 - E3) for the hydrogen atom is approxi...

    Text Solution

    |

  18. With increasing member, the energy difference between adjacent levels ...

    Text Solution

    |

  19. Which one of the following is considered as the main postulate of Bohr...

    Text Solution

    |

  20. The energy of second Bohr orbit of the hydrogen atom is - 328 k J mol^...

    Text Solution

    |