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The density of ice at 0^(@)C is 0.99987g...

The density of ice at `0^(@)C` is `0.99987g//"cc"` . The work done for melting mole of ice at `1.00` bar (assuming work is done only due to expansion) is approximately

A

`0.17J`

B

`1.7xx10^(3)J`

C

`1.7xx10^(-6)J`

D

can't be determined

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AI Generated Solution

The correct Answer is:
To find the work done for melting one mole of ice at 1 bar, we can follow these steps: ### Step 1: Understand the Work Done Formula The work done (W) during a process at constant pressure can be calculated using the formula: \[ W = -P \Delta V \] However, since we are considering work done due to expansion, we will use: \[ W = P \Delta V \] ### Step 2: Calculate the Volume of Ice We know the density of ice at \(0^{\circ}C\) is \(0.99987 \, \text{g/cm}^3\). The molar mass of ice (water) is approximately \(18 \, \text{g/mol}\). To find the volume of 1 mole of ice: \[ \text{Volume of ice} = \frac{\text{mass}}{\text{density}} = \frac{18 \, \text{g}}{0.99987 \, \text{g/cm}^3} \] Calculating this gives: \[ \text{Volume of ice} \approx 18.0002 \, \text{cm}^3 \] ### Step 3: Calculate the Volume of Water Next, we need to calculate the volume of the water produced from melting the ice. The density of water at \(0^{\circ}C\) is approximately \(1.000 \, \text{g/cm}^3\). To find the volume of 1 mole of water: \[ \text{Volume of water} = \frac{18 \, \text{g}}{1.000 \, \text{g/cm}^3} = 18 \, \text{cm}^3 \] ### Step 4: Calculate the Change in Volume The change in volume (\(\Delta V\)) when ice melts into water is: \[ \Delta V = \text{Volume of water} - \text{Volume of ice} \] \[ \Delta V = 18 \, \text{cm}^3 - 18.0002 \, \text{cm}^3 \] \[ \Delta V \approx -0.0002 \, \text{cm}^3 \] ### Step 5: Convert Volume to Cubic Meters Since \(1 \, \text{cm}^3 = 10^{-6} \, \text{m}^3\): \[ \Delta V \approx -0.0002 \, \text{cm}^3 \times 10^{-6} \, \text{m}^3/\text{cm}^3 = -2.0 \times 10^{-10} \, \text{m}^3 \] ### Step 6: Calculate Work Done Now, substituting the values into the work done formula: - Pressure \(P = 1 \, \text{bar} = 10^5 \, \text{Pa}\) - Change in volume \(\Delta V = -2.0 \times 10^{-10} \, \text{m}^3\) Thus, \[ W = P \Delta V = (10^5 \, \text{Pa}) \times (-2.0 \times 10^{-10} \, \text{m}^3) \] \[ W = -0.02 \, \text{J} \] ### Step 7: Final Result The work done for melting one mole of ice at 1 bar is approximately: \[ W \approx 0.02 \, \text{J} \]

To find the work done for melting one mole of ice at 1 bar, we can follow these steps: ### Step 1: Understand the Work Done Formula The work done (W) during a process at constant pressure can be calculated using the formula: \[ W = -P \Delta V \] However, since we are considering work done due to expansion, we will use: \[ W = P \Delta V \] ...
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A2Z-CHEMICAL THERMODYNAMICS-Section D - Chapter End Test
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