Home
Class 11
CHEMISTRY
Evaluate DeltaU at 500K for the process ...

Evaluate `DeltaU` at `500K` for the process
`Mg(s)+2HC1(g)=MgC1_(2)(s)+H_(2)(g)`
`DeltaH=-109Kcal`
The volume change of solids to be ignored

A

`-204Kcal`

B

`-108Kcal`

C

`-9Kcal`

D

`+9Kcal`

Text Solution

Verified by Experts

The correct Answer is:
C

`DeltaH=DeltaV+Deltan_(g)RT`
`-109=DeltaV+((-1xx2xx500)/(1000))Kcal`
`-109=DeltaU-1Kcal`
`DeltaU=-109+1=-108Kcal`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL THERMODYNAMICS

    A2Z|Exercise Work, Internal Energy And Enthalpy|76 Videos
  • CHEMICAL THERMODYNAMICS

    A2Z|Exercise Entropy, Gibb'S Energy And Spontaneity Of Process|52 Videos
  • CHEMICAL EQUILIBRIUM

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • CLASSIFICATION OF ELEMENTS AND PERIODICITY OF PROPERTIES

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

The heat change accompanying the reaction 2H_(2)(g)+O_(2)(g) to 2H_(2)O(l) : DeltaH= -136kcal is called

The heat change for the following reaction at 298 K and constant pressure is +7.3 kcal A_(@)B(s)to2A(s)+(1)/(2)B_(2)(g) , DeltaH=+7.3 kcal The heat change at constant volume would be

Given that: i. C(s) + O_(2)(g) rarr CO_(2)(g) , DeltaH =- 94.05 kcal ii. H_(2)(g) +(1)/(2) O_(2)(g) rarr H_(2)O(l), DeltaH =- 68.32 kcal iii. C_(2)H_(2)(g) +(5)/(2) O_(2)(g) rarr 2CO_(2)(g) +H_(2)O(l),DeltaH =- 310.62 kcal The heat of formation fo acetylene is

Assertion : For the change, H_(2)O_((l))rarr H_(2)O_((s)),DeltaH=DeltaU . Reason : No enthalpy change is involved in this process.

Given that O(g)+e^(-)rarrO^(-)(g) , DeltaH=34Kcal mol^(-1) O(g)+2e^(-)(g)rarrO^(2-)(g) , DeltaH=168Kcal mol^(-1) The enthalply change for the reaction O^(-)(g)+e^(-)rarrO^(2-)(g) is

A2Z-CHEMICAL THERMODYNAMICS-Section D - Chapter End Test
  1. Evaluate DeltaU at 500K for the process Mg(s)+2HC1(g)=MgC1(2)(s)+H(2...

    Text Solution

    |

  2. Calcualte the maximum efficiency of an engine operating between110^(@)...

    Text Solution

    |

  3. Five moles of anideal gas expends reversily from a volume of8dm^(3)at ...

    Text Solution

    |

  4. Entropy change involve in conversion of 1 mole of liquid water at 373K...

    Text Solution

    |

  5. What is the value ofDeltaE(heat change at constant volume)for reversib...

    Text Solution

    |

  6. Which of the statement is correct?

    Text Solution

    |

  7. The specific heats of iodine vapour and solid are 0.031 and 0.055 cal/...

    Text Solution

    |

  8. Bond dissociation energy ofCH(3)-Hbond is103Kcalmol^(-1)and0.055cal//g...

    Text Solution

    |

  9. Given,H(s)(g)=2H(g)Delta(H-H)=103kcalmol^(-1) CH(4)(g)=CH(3)(g)+H(g...

    Text Solution

    |

  10. For the combustion of n-octane C(8)H(18)+O(2)rarrCO(2)+H(2)O at 25^(...

    Text Solution

    |

  11. The enthapies of neutralisation of HClO(4)and Cl(3)C-COOHare -13.5kc...

    Text Solution

    |

  12. The work done in erge for the reversible expansion of 1 mole of an ide...

    Text Solution

    |

  13. If 900J//g of heat is exchanged at boiling point of water then water...

    Text Solution

    |

  14. The enthalpy of formation of H(2)O(l) is -280.70 kJ/mol and enthalpy o...

    Text Solution

    |

  15. One gram sample of NH(4)NO(3) is decomposed in a bomb calorimeter. The...

    Text Solution

    |

  16. Calculate the resonance enegry of N(2)O form the following data Delt...

    Text Solution

    |

  17. If a 298K the bond energies of C-H,C-C,C=C and H-H bonds are respectiv...

    Text Solution

    |

  18. The enthalpies of formation of Al(2)O(3) and Cr(2)O(3) are -1596KJ and...

    Text Solution

    |

  19. "The quanity of heat which must be supplied to decompose a compound in...

    Text Solution

    |

  20. C("graphite")+O(2)(g)rarrCO(2)(g) deltaH=-94.05Kcalmol^(-1) C("dia...

    Text Solution

    |

  21. Which of the follwing has lowest fusion temperature ?

    Text Solution

    |