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100ml of 0.2 M H(2)SO(4) is added to 100...

`100ml` of `0.2 M H_(2)SO_(4)` is added to `100 ml` of `0.2 M NaOH`. The resulting solution will be

A

Acidic

B

Basic

C

Neutral

D

Slightly basic

Text Solution

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The correct Answer is:
To solve the problem of determining the resulting solution when `100 ml` of `0.2 M H₂SO₄` is mixed with `100 ml` of `0.2 M NaOH`, we will follow these steps: ### Step 1: Calculate the milliequivalents of H₂SO₄ - H₂SO₄ is a diprotic acid, meaning it can donate 2 protons (H⁺ ions). - The formula to calculate milliequivalents (meq) is: \[ \text{meq} = \text{Molarity (M)} \times \text{Volume (L)} \times n \] where \( n \) is the number of protons the acid can donate. - For H₂SO₄: \[ \text{meq of H₂SO₄} = 0.2 \, \text{M} \times 0.1 \, \text{L} \times 2 = 0.04 \, \text{equivalents} = 40 \, \text{meq} \] ### Step 2: Calculate the milliequivalents of NaOH - NaOH is a strong base that can donate 1 hydroxide ion (OH⁻). - Using the same formula: \[ \text{meq of NaOH} = 0.2 \, \text{M} \times 0.1 \, \text{L} \times 1 = 0.02 \, \text{equivalents} = 20 \, \text{meq} \] ### Step 3: Determine the excess H⁺ ions - The total milliequivalents of H⁺ from H₂SO₄ is 40 meq, and the total milliequivalents of OH⁻ from NaOH is 20 meq. - The remaining H⁺ ions after neutralization can be calculated as: \[ \text{Excess H⁺} = \text{meq of H₂SO₄} - \text{meq of NaOH} = 40 \, \text{meq} - 20 \, \text{meq} = 20 \, \text{meq} \] ### Step 4: Calculate the total volume of the solution - The total volume after mixing is: \[ \text{Total Volume} = 100 \, \text{ml} + 100 \, \text{ml} = 200 \, \text{ml} = 0.2 \, \text{L} \] ### Step 5: Calculate the concentration of H⁺ ions in the resulting solution - The concentration of H⁺ ions is given by: \[ \text{Concentration of H⁺} = \frac{\text{Excess H⁺}}{\text{Total Volume}} = \frac{20 \, \text{meq}}{200 \, \text{ml}} = \frac{20}{200} = 0.1 \, \text{M} \] ### Step 6: Calculate the pH of the solution - The pH can be calculated using the formula: \[ \text{pH} = -\log[\text{H⁺}] \] where \([\text{H⁺}] = 0.1 \, \text{M}\): \[ \text{pH} = -\log(0.1) = 1 \] ### Conclusion Since the pH of the resulting solution is 1, which is less than 7, the solution is acidic. ### Final Answer The resulting solution will be **Acidic**. ---

To solve the problem of determining the resulting solution when `100 ml` of `0.2 M H₂SO₄` is mixed with `100 ml` of `0.2 M NaOH`, we will follow these steps: ### Step 1: Calculate the milliequivalents of H₂SO₄ - H₂SO₄ is a diprotic acid, meaning it can donate 2 protons (H⁺ ions). - The formula to calculate milliequivalents (meq) is: \[ \text{meq} = \text{Molarity (M)} \times \text{Volume (L)} \times n \] ...
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A2Z-IONIC EQUILIBIUM-Section D - Chapter End Test
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  2. If the degree of ionization of water be 1.8xx10^(-9) at 298 K. Its ion...

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  3. When a solution of benzoic acid was titrated with NaOH the pH of the s...

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  4. 10^(-2) mole of NaOH was added to 10 litres of water. The pH will chan...

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  5. If an acidic indicator HIn ionies as HInhArrH^(+)+In^(-). To which max...

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  6. Let the solubilities of AgCl in pure water be 0.01 M CaCl(2), 0.01 M N...

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  7. What would be the pH of an ammonia solution if that of an acetic acid ...

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  8. pH of saturated solution of Ba(OH)(2) is 12. The value of solubility p...

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  9. The hydrolysis constant for ZnCl(2) will be where K(b) is effective ...

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  10. In which case pH will not change on dilution

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  11. M(OH)(X) has K(SP) 4xx10^(-12) and solubility 10^(-4) M. The value of ...

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  12. 1 M benzoic acid (pKa=4.20) and 1 M C6H5COONa solutions are given sepa...

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  13. The pH of an aqueous solution of 0.1 M solution of a weak monoprotic a...

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  14. pH of a 10^(-10) M NaOH is nearest to

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  15. The dissocication constant of a weak acid is 1.0xx10^(-5), the equilib...

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  16. The pH of 0.1 M solution of the following salts increases in the order

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  17. In the equilibrium A^(-)+H(2)OhArrHA+OH^(-)(K(a)=1.0xx10^(-5)). The de...

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  18. The sulphide ion concentration [S^(2-)] in saturated H(2)S solution is...

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  19. The K(sp) of CuS, Ag(2)S and HgS are 10^(-31), 10^(-44) and 10^(-54) r...

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  20. For a weak acid HA with dissociation constant 10^(-9), pOH of its 0.1 ...

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  21. The concentration of [H^(+)] and concentration of [OH^(-)] of a 0.1 aq...

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