Home
Class 11
CHEMISTRY
For NH(3), K(b)=1.8xx10^(-5). K(a) for N...

For `NH_(3)`, `K_(b)=1.8xx10^(-5)`. `K_(a)` for `NH_(4)^(+)` would be

A

`1.8xx10^(5)`

B

`5.56xx10^(5)`

C

`1.8xx10^(10)`

D

`5.56xx10^(-10)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the acid dissociation constant \( K_a \) for \( NH_4^+ \) (the conjugate acid of ammonia \( NH_3 \)), we can use the relationship between the base dissociation constant \( K_b \) and the acid dissociation constant \( K_a \) through the ion product of water \( K_w \). ### Step-by-Step Solution: 1. **Identify the Constants**: - We are given \( K_b \) for ammonia \( NH_3 \): \[ K_b = 1.8 \times 10^{-5} \] - The ion product of water \( K_w \) at 25°C is: \[ K_w = 1.0 \times 10^{-14} \] 2. **Use the Relationship**: - The relationship between \( K_a \), \( K_b \), and \( K_w \) is given by: \[ K_a \times K_b = K_w \] - Rearranging this equation to solve for \( K_a \): \[ K_a = \frac{K_w}{K_b} \] 3. **Substitute the Values**: - Now substitute the known values into the equation: \[ K_a = \frac{1.0 \times 10^{-14}}{1.8 \times 10^{-5}} \] 4. **Perform the Calculation**: - First, calculate the division: \[ K_a = \frac{1.0}{1.8} \times 10^{-14 + 5} = \frac{1.0}{1.8} \times 10^{-9} \] - Simplifying \( \frac{1.0}{1.8} \) gives approximately \( 0.555 \): \[ K_a \approx 0.555 \times 10^{-9} \] - Therefore, we can express this as: \[ K_a \approx 5.56 \times 10^{-10} \] 5. **Final Result**: - The \( K_a \) for \( NH_4^+ \) is: \[ K_a \approx 5.56 \times 10^{-10} \]

To find the acid dissociation constant \( K_a \) for \( NH_4^+ \) (the conjugate acid of ammonia \( NH_3 \)), we can use the relationship between the base dissociation constant \( K_b \) and the acid dissociation constant \( K_a \) through the ion product of water \( K_w \). ### Step-by-Step Solution: 1. **Identify the Constants**: - We are given \( K_b \) for ammonia \( NH_3 \): \[ K_b = 1.8 \times 10^{-5} ...
Promotional Banner

Topper's Solved these Questions

  • IONIC EQUILIBIUM

    A2Z|Exercise Salt Hydrolysis|36 Videos
  • IONIC EQUILIBIUM

    A2Z|Exercise Common Ion Effect, Ksp And Applications|38 Videos
  • IONIC EQUILIBIUM

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • HYDROGEN

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • MOCK TEST

    A2Z|Exercise Mock Test 2|45 Videos

Similar Questions

Explore conceptually related problems

NH_(4)CN is a salt of weak acid HCN(K_(a)=6.2xx10^(-10)) and a weak base NH_(4)OH(K_(b)=1.8xx10^(-5)) . 1 molar solution of NH_(4)CN will be :-

Freshly precipiteated Al and Mg hydroxides are stirred vigorously in a buffer solution containing 0.25M of NH_(4)CI and 0.05M of NH_(4)OH . Calculate [Al^(3+)] and [Mg^(2+)] in solution. K_(b) for NH_(4)OH=1.8xx10^(-5) K_(SP) of Al(OH)_(3)=6xx10^(-32) and K_(SP) of Mg(OH)_(2)=8.9xx10^(-12) .

NH_(4)CN is a salt of weak acid HCN (Ka=6.2xx10^(-10)) and a weak base NH_(4)OH(K^(b)=1.8xx10^(-5)) A one molar solution of NH_(4)CN will be :-

Ag^(+) + NH_(3) ltimplies [Ag(NH_(3))]^(+), k_(1)=6.8 xx 10^(-5) [Ag(NH_(3))]^(+) + NH_(3) ltimplies [Ag(NH_(3))_(2)]^(+) , k_(2) = 1.6xx10^(-3) The formation constant of [Ag(NH_(3))_(2)]^(+) is :

HCN is a weak acid (K_a=6.2xx10^(-10)).NH_4 OH is a weak base (K_b=1.8xx10^(-5)). A 1 M solution of NH_4CN would be

Dissociation constant of NH_(4)OH is 1.8 xx 10^(-5) . The hydrolysis constant of NH_(4)Cl would be

A2Z-IONIC EQUILIBIUM-Ph, Pkw And Ph Mixture Of Acid And Bases
  1. The hydrogen ion concentration of a 10^(-8) M HCl aqueous soultion at ...

    Text Solution

    |

  2. A reaction CaF(2)hArrCa^(2+)+2F^(-) is at equilibrium. If the concentr...

    Text Solution

    |

  3. What molar concentration of ammonia will provide a hydroxyl ion concen...

    Text Solution

    |

  4. An acid solution of pH=6 is diluted 1000 times, the pH of the final so...

    Text Solution

    |

  5. What will be the pH of a solution formed by mixing 40 ml of 0.10 M HCl...

    Text Solution

    |

  6. 2H(2)OhArrH(3)O^(+)+OH^(-) K(w)=1xx10^(-14) at 25^(@)C. Hence, K(a) ...

    Text Solution

    |

  7. Equal volumes of two soultion, one having pH 6 and the other havingpH ...

    Text Solution

    |

  8. A solution is prepared by dissolving 5.6 g of KOH per litre of solutio...

    Text Solution

    |

  9. [OH^(-)] in a solution is 1 mol L^(-1). The pH of the solution is

    Text Solution

    |

  10. If K(a)=10^(-5) for a weak acid, then pK(b) for its conjugate base wou...

    Text Solution

    |

  11. The dissociation constant of an acid is 1xx10^(-5). The pH of its 0.1 ...

    Text Solution

    |

  12. For NH(3), K(b)=1.8xx10^(-5). K(a) for NH(4)^(+) would be

    Text Solution

    |

  13. A solution of HCl contains 0.1920 g of an acid in 0.5 litre of a solut...

    Text Solution

    |

  14. 10^(-6) M NaOH is diluted by 100 times. The pH of diluted base is

    Text Solution

    |

  15. Which statement is not true?

    Text Solution

    |

  16. When rain is accompained by a thunderstorm, the collected rain water w...

    Text Solution

    |

  17. Hydrogen ion concentration in mol//L in a solution of pH=5.4 will be:

    Text Solution

    |

  18. The pK(a) of a weak acid, HA, is 4.80. The pK(b) of a weak base, BOH, ...

    Text Solution

    |

  19. How many litres of water must be added to 1 L of an aqueous solution o...

    Text Solution

    |

  20. An acid HA ionizes as HAhArrH^(+)+A^(-) The pH of 1.0 M solution is 5....

    Text Solution

    |