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At 25^(@)C K(b) for BOH=1.0xx10^(-12).0....

At `25^(@)C K_(b)` for `BOH=1.0xx10^(-12).0.01M` solution of `BOH` has `[OH^(-)]`:

A

`2.0xx10^(-6) mol L^(-1)`

B

`1.0xx10^(-5) mol L^(-1)`

C

`1.0xx10^(-6) mol L^(-1)`

D

`1.0xx10^(-7) mol L^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
D

`BOHhArrB^(+)+OH^(-)`
So, the dissociation constant of `BOH` base
`K_(b)=([B^(+)][OH^(-)])/([BOH])` (`i`)
At equilibrium `[B^(+)]=[OH^(-)]`
`:. ([OH^(-)]^(2))/([BOH])`
Given that `K_(b)=1.0xx10^(-12)` and `[BOH]=0.01 M`
Thus, `1.0xx10^(-12)=([OH^(-)]^(2))/(0.01)`
`[OH^(-)]^(2)=1xx0^(-14)`
`[OH^(-)]=1.0xx10^(-7) mol L^(-1)`
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