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When 10 ml of 0.1 M acitec acid (pk(a)=5...

When `10 ml` of `0.1 M` acitec acid `(pk_(a)=5.0)` is titrated against `10 ml` of `0.1M` ammonia solution `(pk_(b)=5.0)`,the equivalence point occurs at `pH`

A

`5.0`

B

`6.0`

C

`7.0`

D

`9.0`

Text Solution

Verified by Experts

The correct Answer is:
C

`pK_(a)= -log K_(a)`, `pK_(b)= -log K_(b)`
`pH=(1)/(2)[logK_(a)+logK_(w)-logK_(b)]`
`=-(1)/(2)[-5+log(1xx10^(-14))-(-5)]`
`= -(1)/(2)[-5-14+5]= -(1)/(2)(-14)=7`
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