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If 10g of V(2)O(5) is dissolved in acid ...

If `10g` of `V_(2)O_(5)` is dissolved in acid and is reduced to `V^(2+)` by zinc metal, how many mole `I_(2)` could be reduced by the resulting solution if it is further oxidised to `VO^(2+)` ions? [Assume no change in state of `Zn^(2+)` ions] (`V=51`, `O=16`, `I=127`)

A

`0.11` mole of `I_(2)`

B

`0.22` mole of `I_(2)`

C

`0.055` mole of `I_(2)`

D

`0.44` mole of `I_(2)`

Text Solution

Verified by Experts

The correct Answer is:
A

Mole of `V_(2)O_(5)=(10)/(51xx2+5xx16)=(10)/(102+80)`
`(10)(182)=.055`
Mole of `V^(+2)=.055xx2`
`=.1098 mol e ~=0.11`
`V^(+2) rarr overset(+4)(VO^(+2))+2e`
`implies Mol es of I_(2)=Mol es of V^(+2)=.11`
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