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Assertion: In the reaction, 3As(2)S(3)+2...

Assertion: In the reaction, `3As_(2)S_(3)+28HNO_(3)+4H_(2)O rarr 6H_(3)SAsO_(4)+9H_(2)SO_(4)+28NO` electrons transferred are `84`.
Reason: As is oxidised from `+3` to `+5` and sulphur from `-2` to `+6`.

A

If both assertion and reason are true and the reason is the correct explanation of the assertion.

B

If both assertion and reason are true but reason is not the correct explantion of the assertion.

C

If assertion is true but reason is false.

D

If assertion is false but reason is true.

Text Solution

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The correct Answer is:
A

`(As^(3+))_(2) rarr 2As^(5+)4e`
`underset([As_(2)S_(3) rarr2As^(5+)3S^(6+)+282]xx3)underline((S^(2-))_(3) rarr 3S^(6+)+24e)`
`[3e+N^(5+) rarr N^(2+)]xx28`
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Statement In the reactions , 3As_(2)S_(3)rarr28HNO_(3)+4H_(2)Orarr6H_(3)AsO_(4)+9H_(2)SO_(4)+28NO electrons transferred are 84 . Explanation As is oxidised from +3 to +5 and sulphur from -2 to +6

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