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The number of moles of K(2)Cr(2)O(7) red...

The number of moles of `K_(2)Cr_(2)O_(7)` reduced by `1 mol` of `Sn^(2+)` ions is

A

`1//3`

B

`1//6`

C

`2//3`

D

`1`

Text Solution

Verified by Experts

The correct Answer is:
A

`undersetulbar(Cr(2)O_(7)^(2-)+14H^(+)2Sn^(2+) rarr 3Sn^(4+)+2Cr^(3+)+7H_(2)O)(Cr_(2)O_(7)^(2-)+14H^(+)+underset((Sn^(2+) rarr Sn^(4+)+2e^(-))xx3)(6e^(-)to2Cr^(3+)+7H_(2)O)`
It is clear form this equation that `3` moles of `Sn^(2+)` reduce one mole of `Cr_(2)O_(7)^(2-)`, hence `1` mol. Of `Sn^(2+)` will reduce `(1)/(3)`moles of `Cr_(2)O_(7)^(2-)`.
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