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How many total isomers exist for compoun...

How many total isomers exist for compound with composition `C_(4)H_(8)`?

A

`6`

B

`4`

C

`2`

D

`8`

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The correct Answer is:
To determine the total number of isomers for the compound with the molecular formula \(C_4H_8\), we need to consider the structural isomers, geometric (cis-trans) isomers, and cyclic isomers. Here’s the step-by-step solution: ### Step 1: Calculate the Degree of Unsaturation (DU) The degree of unsaturation (DU) can be calculated using the formula: \[ DU = \frac{(2C + 2 + N - H - X)}{2} \] For \(C_4H_8\): - \(C = 4\) - \(H = 8\) - \(N = 0\) (no nitrogen) - \(X = 0\) (no halogens) Substituting the values: \[ DU = \frac{(2 \times 4 + 2 - 8)}{2} = \frac{(8 + 2 - 8)}{2} = \frac{2}{2} = 1 \] This indicates that the compound has one degree of unsaturation, which can be due to either a double bond or a ring. ### Step 2: Identify Structural Isomers 1. **Straight-chain alkene**: - Butene (1-butene) - Isobutene (2-butene) 2. **Geometric Isomers**: - 2-butene can exist as: - Cis-2-butene - Trans-2-butene ### Step 3: Identify Cyclic Isomers 1. **Cyclic Compound**: - Cyclobutane (a ring structure with four carbon atoms) ### Step 4: Count All Isomers Now, let’s summarize the identified isomers: 1. **1-butene** (straight chain) 2. **2-butene** (straight chain, with geometric isomers) - Cis-2-butene - Trans-2-butene 3. **Cyclobutane** (cyclic structure) ### Total Count of Isomers - 1-butene: 1 - 2-butene: 1 (but has 2 geometric forms, so count as 2) - Cyclobutane: 1 Adding these: - 1 (1-butene) + 2 (cis and trans 2-butene) + 1 (cyclobutane) = **Total: 4 isomers** ### Final Answer The total number of isomers for the compound with the composition \(C_4H_8\) is **4**. ---

To determine the total number of isomers for the compound with the molecular formula \(C_4H_8\), we need to consider the structural isomers, geometric (cis-trans) isomers, and cyclic isomers. Here’s the step-by-step solution: ### Step 1: Calculate the Degree of Unsaturation (DU) The degree of unsaturation (DU) can be calculated using the formula: \[ DU = \frac{(2C + 2 + N - H - X)}{2} \] For \(C_4H_8\): ...
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A2Z-SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY-Geometrical Isomerism
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  7. Which of the following has three different stereoisomers?

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  8. Which will form geometrical isomers?

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  9. Which type of isomerism cannot be shown by benzaldoxime?

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  11. How many cyclic isomers exist (structural and geometrical only) for C(...

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  12. Which of the following carbonyls has four different enol isomers ?

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  18. Which compound can show geometrical isomerism?

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  19. Which of the following not show cis-trans isomerism?

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