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How many different stereoisomers exist f...

How many different stereoisomers exist for `1`-chloro-`2`(`3`-chlorocyclobutyl) ethane?

A

`2`

B

`7`

C

`5`

D

`4`

Text Solution

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The correct Answer is:
To determine the number of different stereoisomers for 1-chloro-2-(3-chlorocyclobutyl)ethane, we will follow these steps: ### Step 1: Understand the Structure 1. **Identify the main chain**: The main chain is ethane (C2H6). 2. **Identify the substituents**: There is a chlorine atom (Cl) at the first carbon (1-chloro) and a cyclobutyl group with another chlorine atom at the second carbon (2-(3-chlorocyclobutyl)). ### Step 2: Draw the Structure 1. **Draw ethane**: Start with the two carbon atoms connected by a single bond. 2. **Add the 1-chloro substituent**: Attach a chlorine atom to the first carbon. 3. **Add the 2-(3-chlorocyclobutyl) substituent**: Draw a cyclobutane ring (4 carbon atoms in a square) and attach it to the second carbon. Add a chlorine atom to one of the carbons in the cyclobutane ring. ### Step 3: Identify Stereocenters 1. **Check for stereocenters**: A stereocenter is a carbon atom bonded to four different groups. In this case, the second carbon (C2) is bonded to: - The cyclobutyl group (which has different substituents) - The ethyl group (C1) - A hydrogen atom - The chlorine atom Since C2 has four different groups, it is a stereocenter. ### Step 4: Determine Geometric Isomers 1. **Geometric isomerism**: The presence of a double bond or a ring can lead to cis/trans isomerism. In this case, the cyclobutane ring can have two configurations (cis and trans) based on the position of the chlorine atom and the hydrogen atom. ### Step 5: Calculate Total Stereoisomers 1. **Count the combinations**: - For the stereocenter at C2, there are 2 configurations (R/S). - For the cyclobutane ring, there are also 2 configurations (cis/trans). Thus, the total number of stereoisomers can be calculated as: \[ \text{Total Stereoisomers} = 2 \text{ (from C2)} \times 2 \text{ (from cyclobutane)} = 4 \] ### Conclusion The total number of different stereoisomers for 1-chloro-2-(3-chlorocyclobutyl)ethane is **4**. ---

To determine the number of different stereoisomers for 1-chloro-2-(3-chlorocyclobutyl)ethane, we will follow these steps: ### Step 1: Understand the Structure 1. **Identify the main chain**: The main chain is ethane (C2H6). 2. **Identify the substituents**: There is a chlorine atom (Cl) at the first carbon (1-chloro) and a cyclobutyl group with another chlorine atom at the second carbon (2-(3-chlorocyclobutyl)). ### Step 2: Draw the Structure 1. **Draw ethane**: Start with the two carbon atoms connected by a single bond. ...
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