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Which of the following has three differe...

Which of the following has three different stereoisomers?

A

`2,4`-hexadiene

B

`1,3`-butadiene

C

`2,5`-hexadiene

D

`2,4`-heptadiene

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds has three different stereoisomers, we will analyze the structures of the compounds mentioned in the question. ### Step-by-Step Solution: 1. **Identify the Compounds**: The question mentions several compounds, including 2,4-hexadiene, 1,3-butadiene, 2,5-hexadiene, and 2,4-heptadiene. 2. **Draw the Structure of 2,4-Hexadiene**: - The structure of 2,4-hexadiene can be represented as: ``` CH3-CH=CH-CH=CH-CH3 ``` - Here, the double bonds are located at the 2nd and 4th carbon atoms. 3. **Analyze Stereoisomerism**: - For 2,4-hexadiene, we can have cis and trans configurations around each double bond. - The first double bond (C2=C3) can be either cis (both substituents on the same side) or trans (substituents on opposite sides). - The second double bond (C4=C5) can also be either cis or trans. 4. **Count the Stereoisomers**: - For the first double bond (C2=C3), we have two possibilities: cis and trans. - For the second double bond (C4=C5), we again have two possibilities: cis and trans. - However, due to symmetry, some combinations will lead to identical structures. - The combinations yield three unique stereoisomers: 1. **Cis-Cis** (both double bonds in the cis configuration) 2. **Cis-Trans** (first double bond cis, second trans) 3. **Trans-Trans** (both double bonds in the trans configuration) 5. **Evaluate Other Compounds**: - **1,3-Butadiene**: This compound can only form two stereoisomers (cis and trans) due to the presence of only one double bond. - **2,5-Hexadiene**: This compound has no stereoisomers because it does not have any double bonds that can exhibit stereochemistry. - **2,4-Heptadiene**: Similar to 2,4-hexadiene, it can only form two stereoisomers. 6. **Conclusion**: - The only compound that can form three different stereoisomers is **2,4-hexadiene**. ### Final Answer: **The compound that has three different stereoisomers is 2,4-hexadiene.**

To determine which of the given compounds has three different stereoisomers, we will analyze the structures of the compounds mentioned in the question. ### Step-by-Step Solution: 1. **Identify the Compounds**: The question mentions several compounds, including 2,4-hexadiene, 1,3-butadiene, 2,5-hexadiene, and 2,4-heptadiene. 2. **Draw the Structure of 2,4-Hexadiene**: - The structure of 2,4-hexadiene can be represented as: ...
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