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A binary liquid solution of n-heptane an...

A binary liquid solution of n-heptane and ethyl alcohol is prepared which of the following statements correctly represents the behaviour of this liquid solution?

A

The solution formed is an ideal solution

B

The solution formed is a non - ideal solution with positive deviations from Raoult's law.

C

The solution formed is a non- ideal solution with negative deviations from Raoult's law

D

Normal-heptane exhibits postive deviations , whereas ethyl alcohol exhibits negative deviations from Raoult's law

Text Solution

Verified by Experts

The correct Answer is:
B

Intermolecular forces among molecules of n- heptane and ethyl alcohols are weaker than among hexane and among ethyl alcohols molecules,`:.`V.P. of solution is ,ore than V.P.of pure solvents.
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Liquid Solutions - 5

A2Z-SOLUTIONS-Raoult'S Law, Ideal And Non-Ideal Solutions, Azeotropes
  1. A liquid is kept in a closed vessel. If a glass plate (negligible mass...

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  2. Given at 350K, p(A)^@=300 "torr" and p(B)^@=800 "torr" the composition...

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  3. The vapour pressure of the solution of two liquids A(P^@=80mm) and B(P...

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  4. In mixture A and B ,components show -ve deviations as:

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  5. If liquids A and B from an ideal solution, than :

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  6. Which liquids pair shows a positive deviation from Raoult's law?

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  7. Benzene and toluene form nearly ideal solutions.At 20^@C, the vapour p...

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  8. A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of...

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  9. At 80^@C, the vapour pressure of pure liquid A is 520 mm Hg and that o...

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  10. The vapour pressure of water at20^@Cis 17.5mmHg.if 18gof glucose (C(6)...

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  11. For A and B to form an ideal solution which of the following condition...

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  12. A binary liquid solution of n-heptane and ethyl alcohol is prepared wh...

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  13. The mole fraction of toluene in vapour phase which is in equlibrium wi...

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  14. Two liquids are mixed together to from a mixture which boils at same t...

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  15. At35^@C the vapour of pure chlorofrom si 0.359atm and that of pure ace...

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  16. When a solution of CHCI(3) is mixed with a solution of acetone,DeltaV(...

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  17. The vapour pressure of hexane (C(6)H(14)) and heptane (C(7)H(16)) at 5...

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  18. Benzene (C(6)H(6),78g//mol)and toluene (C(7)H(8),92g//mol)from an idea...

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  19. At 25^@Cthe vapour prssure of benzene ,C(6)H(6)(78g//mol e),is 93.2 to...

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  20. At 334K the vapour pressure of benzene(C(6)H(6))is0.526atm and that of...

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