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A mineral having the formula XY(2) crys...

A mineral having the formula `XY_(2)` crystaillises in the cubic closed packed lattic with the A- atoms occupaying the lattice point .Fraction of the betradral sites occupired by B- atoms is

A

`1.00`

B

`0.52`

C

`0.68`

D

`0.74`

Text Solution

Verified by Experts

The correct Answer is:
A

`AB_(2)` cryswtanllises as cubic packed (ccp)
This `A^(2+)` is surrounded by edge `B^(-)`
and `B` is surrounding by four `A^(2 +)`
Thus coordination number of `A^(2+) = 8`
Coordination number of `B^(-) = 4`
Number of atoms as trtahoudral in small of unit of atoms `B= 4`
Thus fraction occepaid `= (4)/(4) = 1 (100%)`
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