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Asseration: Equivalent mass of H(2)SO(4)...

Asseration: Equivalent mass of `H_(2)SO_(4)` in lead storage battery is `49`.
Reason: In lead storage battery, `H_(2)SO_(4)` acts both as oxidant and reductant.

A

If both the asseration and reason are ture and reason is the true explation of the assertion.

B

If both the asseration and reason are ture but the reason is not the correct explanation of assertion.

C

If the asseration is true but reason is false.

D

If asseration is false bit reason is true.

Text Solution

Verified by Experts

The correct Answer is:
D

Anode:
`Ph(s)+HSO_(4)^(-)+H_(2)OrarrPbSO_(4)+2e+H_(3)O^(+)`
Cathode:
`PhO_(2)(s)+HSO_(4)^(-)+3H_(3)O^(+)+2erarrPbSO_(4)(s)+5H_(2)o`
Net `Pb+2HSO_(4)^(-)+2H_(3)O^(+)+PbO_(2)rarrPbSO_(4)+4H_(2)O`
Thus, `2H_(2)SO_(4)` consumes `2` electrons.
`:.E. mass=("molar mass")/(1)=98`
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