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Which of the following pairs is coloured...

Which of the following pairs is coloured in aqueous solution?

A

`Sc^(3+), Co^(2+)`

B

`Ni^(2+),Cu^(+)`

C

`Ni^(2+), Ti^(3+)`

D

`Sc^(3+),Ti^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
C

`._(28)Ni = 2 s^(2) 2s^(2) 2p^(6) 3 s^(2) 3 p^(6) 3 d^(8) 4 s^(2)`
`Ni^(2+) = 1s^(2) 2s^(2) 2P^(6) 3s^(2) 3P^(6) 3 d^(8)`

`._(22)Ti = 1 s^(2) 2 s^(2) 2 p^(6) 3 s^(2) 3 p^(6) 3 d^(2) 4 s^(2)`
`Ti^(3+) = 1 s^(2) 2 s^(2) 2p^(6) 3 s^(2) 3 p^(6) 3 d^(1)`
Hence, `Ni^(2+)` and `Ti^(3+)` are coloured in aqueous solution due to the presence of upaired electrons in d-subshell.
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