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Which among the following will be named ...

Which among the following will be named as dibromidobis-(ethylenediamine) chromium (III) bromide?

A

(a) `[Cr(en)_3]Br_3`

B

(b) `[Cr(en)_2Br_2]Br`

C

(c) `[Cr(en)Br_4]^(-)`

D

(d) `[Cr(en)Br_2]Br`

Text Solution

Verified by Experts

The correct Answer is:
B

Two Br, two (en) and one Cr are parts of complex. Charge on the complex is
`{:(2(Br),=,-2,,),(2(en),=,0,,), (1(Cr),=,+3,,):}}=+1`
Thus, complex ion is `[Cr(en)_2Br_2]^(+)`.
Since, anion is bromide thus, complex is `[Cr(en)_2Br_2]Br`.
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