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Among the ligands NH3, en, CN^(-) and CO...

Among the ligands `NH_3`, `en`, `CN^(-)` and `CO`, the correct order of their increasing field strength, is

A

(a) `COltNH_3ltenltCN^(-)`

B

(b) `NH_3ltenltCN^(-)ltCO`

C

(c) `CN^(-)ltNH_3ltCOlten`

D

(d) `enltCN^(-)ltNH_3ltCO`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of increasing ligand field strength among the ligands \(NH_3\), \(en\) (ethylenediamine), \(CN^-\), and \(CO\), we can refer to the spectrochemical series, which ranks ligands based on their ability to split the d-orbitals in transition metal complexes. ### Step-by-Step Solution: 1. **Understanding Ligand Field Strength**: - Ligand field strength refers to the ability of a ligand to cause splitting of the d-orbitals in a transition metal complex. Strong field ligands cause a larger splitting of the d-orbitals compared to weak field ligands. 2. **Referencing the Spectrochemical Series**: - The spectrochemical series is a list that ranks ligands based on their field strength. The order from weakest to strongest field ligands is as follows: - \(I^- < Br^- < SCN^- < Cl^- < S^{2-} < F^- < OH^- < C_2O_4^{2-} < H_2O < EDTA^{4-} < NH_3 < en < NO_2^- < CN^- < CO\) 3. **Identifying the Position of Each Ligand**: - From the spectrochemical series, we can identify the positions of the given ligands: - \(NH_3\) is positioned before \(en\), indicating that \(NH_3\) has a lower field strength than \(en\). - \(en\) is positioned before \(CN^-\), indicating that \(en\) has a lower field strength than \(CN^-\). - \(CN^-\) is positioned before \(CO\), indicating that \(CN^-\) has a lower field strength than \(CO\). 4. **Arranging the Ligands in Order of Increasing Field Strength**: - Based on the positions identified: - The order of increasing field strength is: \[ NH_3 < en < CN^- < CO \] ### Final Answer: The correct order of increasing field strength among the ligands \(NH_3\), \(en\), \(CN^-\), and \(CO\) is: \[ NH_3 < en < CN^- < CO \]

To determine the correct order of increasing ligand field strength among the ligands \(NH_3\), \(en\) (ethylenediamine), \(CN^-\), and \(CO\), we can refer to the spectrochemical series, which ranks ligands based on their ability to split the d-orbitals in transition metal complexes. ### Step-by-Step Solution: 1. **Understanding Ligand Field Strength**: - Ligand field strength refers to the ability of a ligand to cause splitting of the d-orbitals in a transition metal complex. Strong field ligands cause a larger splitting of the d-orbitals compared to weak field ligands. 2. **Referencing the Spectrochemical Series**: ...
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