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Match List-I (Complexes) with List-II (H...

Match List-I (Complexes) with List-II (Hybridization) of central atom and select the correct answer using the codes given below the lists:
`{:(,List-I,,,List-II),(A,Ni(CO)_4,,1.,sp^3),(B,[Ni(CN)_4]^(2-),,2.,dsp^2),(C,[Fe(CN)_6]^(4-),,3.,sp^3d^2),(D,[MnF_6]^(4-),,4.,d^2sp^3):}`

A

(a) `{:(A,B,C,D,),(1,3,2,4,):}`

B

(b) `{:(A,B,C,D,),(5,2,4,3,):}`

C

(c) `{:(A,B,C,D,),(5,3,2,4,):}`

D

(d) `{:(A,B,C,D,),(1,2,4,3,):}`

Text Solution

Verified by Experts

The correct Answer is:
D

`[Ni(CO)_4]=sp^3`, `[Ni(CN)_4]^(2-)=dsp^2`, `[Fe(CN)_6]^(4-)=d^2sp^3`, `[MnF_6]^(4-)=sp_3d^2`.
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A2Z-COORDINATION COMPOUNDS-Wemer Theory And Vbt
  1. Match List-I (Complexes) with List-II (Hybridization) of central atom ...

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  2. Match List-I (complex ions) with List-II (number of unpaired electrons...

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  3. Ag^(o+) forms complexes:[Ag(NH(3))(2)]^(o+),[Ag(CN)(2)]^(Θ),[Ag(S(2)O(...

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  4. The hybridization of Fe in K4[Fe(CN)6] complex is:

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  5. The structure of iron pentacarbonyl is:

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  6. [Cr(NH3)6]^(3+) ion is:

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  7. In hexacyanidomanganate(II) ion the Mn atom assumes d^(2)sp^(3)- hybri...

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  8. Which is true in the case of [Ni(CO)4] complex?

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  9. Which one of the following is an outer orbital complex and exhibits pa...

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  10. Which of the following complexes exhibits the highest paramagnetic beh...

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  11. A magnetic moment of 1.73 B.M. will be shown by one among the followin...

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  12. A square planar complex is formed by hybridization of which atomic orb...

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  13. Among the following complexes : K(3)[Fe(CN)(6)],[Co(NH(3))(6)]Cl(3) , ...

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  14. Consider the follwing complexes ion P,Q and R P =[FeF(6)]^(3-), Q=[V...

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  15. Among the following ions which one has the highest paramagnetism?

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  16. The reaction [Fe(CNS)6]^(3-)rarr[FeF6]^(3-) takes place with:

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  17. dsp^2-hybridization is found in

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  18. The primary valency of iron in K4[Fe(CN)6] is

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  19. The magnetic moment of K3[Fe(CN)6] is found to be 1.7 B.M. How many un...

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  20. [Cr(H2 O)6]Cl3 (at no. of Cr = 24) has a magnetic moment of 3.83 B.M. ...

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