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What is the chief product obtained when ...

What is the chief product obtained when `n-`butane is treated with `Br_(2)` in the presence of light at `130^(@)C`?

A

`CH_(3)CH_(2)CH_(2)CH_(2)Br`

B

`Ch_(3) CH_(2)CHBrunderset(CH_3)underset(|)CHBr`

C

`Ch_(3) -CH_(2) HBrunderset(CH_2Br)underset(|)CHBr`

D

`Ch_(3) -CH_(2) HBrunderset(CH_3)underset(|)CBr_(2)`

Text Solution

Verified by Experts

The correct Answer is:
B

The reaction proceeds via free radical mechanism and rate of abstraction of `2^(@)` hydrogen is faster
As `2^(@)` free radical is more stable tnan `1^(@)` , so `CH_(3) CH_(2) CH(Br)CH_(3) ` would be formed .
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