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The oxidation state of Fe in K(4)[Fe(CN)...

The oxidation state of Fe in `K_(4)[Fe(CN)_(6)]` is

A

`+2`

B

`+6`

C

`+3`

D

`+4`

Text Solution

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The correct Answer is:
To determine the oxidation state of iron (Fe) in the compound \( K_4[Fe(CN)_6] \), we can follow these steps: ### Step 1: Identify the components of the compound The compound consists of potassium ions (K\(^+\)) and the complex ion \([Fe(CN)_6]^{4-}\). ### Step 2: Assign known oxidation states - Potassium (K) is an alkali metal and has an oxidation state of +1. - The cyanide ion (CN\(^-\)) is a ligand and has an oxidation state of -1. ### Step 3: Set up the equation Let the oxidation state of iron (Fe) be \( x \). The complex ion \([Fe(CN)_6]\) has a total charge of -4. We can express this relationship as follows: \[ \text{Total charge} = \text{oxidation state of K} + \text{oxidation state of Fe} + \text{oxidation state of CN} \] The equation can be set up as: \[ 4(+1) + x + 6(-1) = 0 \] ### Step 4: Substitute known values Substituting the known values into the equation gives us: \[ 4(1) + x + 6(-1) = 0 \] This simplifies to: \[ 4 + x - 6 = 0 \] ### Step 5: Solve for \( x \) Now, we can solve for \( x \): \[ x - 2 = 0 \] \[ x = +2 \] ### Conclusion The oxidation state of iron (Fe) in \( K_4[Fe(CN)_6] \) is +2. ---

To determine the oxidation state of iron (Fe) in the compound \( K_4[Fe(CN)_6] \), we can follow these steps: ### Step 1: Identify the components of the compound The compound consists of potassium ions (K\(^+\)) and the complex ion \([Fe(CN)_6]^{4-}\). ### Step 2: Assign known oxidation states - Potassium (K) is an alkali metal and has an oxidation state of +1. - The cyanide ion (CN\(^-\)) is a ligand and has an oxidation state of -1. ...
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Knowledge Check

  • K_(4)[Fe(CN)_(6)] is a

    A
    double salt
    B
    complex compound
    C
    neutral molecule
    D
    none of thes .
  • The oxidation number of Fe in K_(4) [Fe(CN_(6))] is -

    A
    `+6`
    B
    `+4`
    C
    `+3`
    D
    `+2`
  • Oxidation state of Fe in K_3[Fe(CN)_6] is

    A
    (a) `2`
    B
    (b) `3`
    C
    (c) `0`
    D
    (d) None of these
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