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When ethanol is treated with potassium b...

When ethanol is treated with potassium bromide and concentrated `H_(2)SO_(4)`, ________ is produced.

A

ethyl bromide

B

ethyl hydrogen sulphate

C

ethylene

D

ethane

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The correct Answer is:
To solve the question, "When ethanol is treated with potassium bromide and concentrated H₂SO₄, ________ is produced," we can follow these steps: ### Step 1: Identify the Reactants - The reactants in this reaction are ethanol (C₂H₅OH), potassium bromide (KBr), and concentrated sulfuric acid (H₂SO₄). ### Step 2: Understand the Role of Concentrated H₂SO₄ - Concentrated sulfuric acid acts as a dehydrating agent and a catalyst in this reaction. It helps in converting the alcohol (ethanol) into a more reactive form by protonating the hydroxyl group (-OH), making it a better leaving group. ### Step 3: Protonation of Ethanol - When ethanol is treated with concentrated H₂SO₄, the -OH group of ethanol gets protonated, forming an oxonium ion (C₂H₅OH₂⁺). This step increases the electrophilicity of the carbon atom bonded to the -OH group. ### Step 4: Formation of Carbocation - The protonation leads to the departure of a water molecule (H₂O), resulting in the formation of a carbocation (C₂H₅⁺). This is a key step in the mechanism. ### Step 5: Nucleophilic Attack by Bromide Ion - The bromide ion (Br⁻) from potassium bromide (KBr) acts as a nucleophile and attacks the carbocation. This forms a new carbon-bromine bond. ### Step 6: Final Product - The final product of this reaction is ethyl bromide (C₂H₅Br). The overall reaction can be summarized as: \[ \text{C₂H₅OH} + \text{KBr} + \text{H₂SO₄} \rightarrow \text{C₂H₅Br} + \text{KHSO₄} + \text{H₂O} \] ### Conclusion - Therefore, when ethanol is treated with potassium bromide and concentrated sulfuric acid, ethyl bromide is produced. ### Final Answer - The blank in the question can be filled with "ethyl bromide." ---
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TARGET PUBLICATION-HALOGEN DERIVATIVES OF ALKANES AND ARENES-EVALUATION TEST
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  2. In the following sequence of reactions, CH(3)CH(2)CH(2)Br overset("K...

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  3. In the following sequence of the reactions : CH(3)CH(2)CH(2)I overse...

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  4. In the reaction CH(3) C -= C^(-) - Na^(+) +(CH(3))(2) CH - Cl to ?...

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  5. Which one of the following is most reactive towards nucleophilic subst...

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  6. Isopropyl chloride undergoes hydrolysis by :

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  7. Which compound shows S(N)1 mechanism as well as optical isomerism ?

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  8. Aryl halides are less reactive towards nucleophilic substitution react...

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  9. Which chloroderivative of benzene among the following would undergo hy...

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  10. o-Toluic acid on reaction with Br(2) + Fe gives

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  11. The reaction of 4-bromobenzyl chloride with NaCN in ethanol leads to :

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  12. Identify 'C' in the following sequence : C(6)H(5)NH(2) underset(273 ...

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  13. The compound CH(3)-underset(Cl)underset(|)overset(CH(3))overset(|)C-CH...

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  14. Benzene reacts with CHCl(3) in the presence of arhydrous AlCl(3) to fo...

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  15. The intermediate during the addition of HI to propene in presence of p...

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  16. The organo bromo compound which shows complete stereochemical inversio...

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  17. An alkyl chloride produces a single alkene when it reacts with sodium ...

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  18. In the following reaction , C(6)H(5)CH(2)Broverset(1.Mg,Ether)underset...

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  19. An alkyl iodide (X) reacts with sodium in ether to form 4,5-diethyloct...

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  20. Which of the following is NOT a haloalkane ?

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