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If an eddothermic reaction occurs sponta...

If an eddothermic reaction occurs spontaneously at constant temperature and pressure, then which of the following is true?

A

`Delta S lt 0`

B

`Delta S gt 0`

C

`Delta H lt 0`

D

`Delta G gt 0`

Text Solution

Verified by Experts

The correct Answer is:
B

According to thermodynamics (at constant `T` and `P`)
`Delta G = Delta H - T Delta S`
For reaction to be spontaneous, `Delta G` should be negative `(lt 0)`. Since the reaction is endothermic, `Delta H` is positive `(gt 0)`. Thus, `T Delta S` should be positive and greater than `Delta S` must be positive `(gt o)`,
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