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The internal energy change when a system...

The internal energy change when a system goes fromk state `A` to `B` is `40 kJ mol^(-1)`. If the system goes from `A` to `B` by a reversible path and returns to state `A` by an irreversible path, what would be the net change in internal energy?

A

zero

B

`40 kJ`

C

`gt 40 kJ`

D

`lt 40 kJ`

Text Solution

Verified by Experts

The correct Answer is:
A

Internal energy is a state function. Thus,
`Delta U = U_(f) - U_(i)`
Since the system returns to its initial state, `U_(f) = U_(i)`. Hence, `Delta U = 0`
It does not matter what path is followed.
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